Decomposition and Oxidation Reactions of Aliphatic Nitro Compounds in Supercritical Water Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2005, Volume: 46, Number: 6, Pages: 821-825 Pages count : 5 DOI: 10.1007/s10975-005-0141-5 | ||||
Tags | Oxidation; Catalysis; Carbon Atom; Oxidation Reaction; Reaction Kinetic | ||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 01-03-32866 |
2 | International Science and Technology Center | 2383 |
Abstract:
The reaction kinetics of nitromethane, nitroethane, and 1-nitropropane decomposition and oxidation in supercritical water near the critical point was studied in a flow reactor. The reaction rate constants were calculated assuming first-order reaction. It was found that pressure has a considerable effect on the rates of decomposition of the above nitrogen-containing compounds in supercritical water over a wide pressure range. The reactivity of the above aliphatic nitro compounds in supercritical water in decomposition reactions decreased and in oxidation reactions increased with an increasing number of carbon atoms.
Cite:
Anikeev V.I.
, Ermakova A.
, Goto M.
Decomposition and Oxidation Reactions of Aliphatic Nitro Compounds in Supercritical Water
Kinetics and Catalysis. 2005. V.46. N6. P.821-825. DOI: 10.1007/s10975-005-0141-5 WOS Scopus РИНЦ
Decomposition and Oxidation Reactions of Aliphatic Nitro Compounds in Supercritical Water
Kinetics and Catalysis. 2005. V.46. N6. P.821-825. DOI: 10.1007/s10975-005-0141-5 WOS Scopus РИНЦ
Original:
Аникеев В.И.
, Ермакова А.
, Гото М.
Реакции разложения и окисления алифатических нитросоединений в сверхкритической воде
Кинетика и катализ. 2005. Т.46. №6. С.868-872. RSCI РИНЦ
Реакции разложения и окисления алифатических нитросоединений в сверхкритической воде
Кинетика и катализ. 2005. Т.46. №6. С.868-872. RSCI РИНЦ
Dates:
Submitted: | Mar 3, 2004 |
Published print: | Nov 1, 2005 |
Identifiers:
Web of science | WOS:000234409400006 |
Scopus | 2-s2.0-30344467579 |
Elibrary | 13492893 |
Chemical Abstracts | 2006:18581 |
Chemical Abstracts (print) | 145:188320 |
OpenAlex | W2015087063 |