Determination of the Activation Energies of Ethylene Polymerization on Titanium-Magnesium Catalysts: Experiment and Mathematical Modeling Full article
Conference |
Monolith honeycomb supports and catalysts. Post conference seminar of Memorial G.K. Boreskov conference "Catalysis on the Eve of the XXI Century. Science and Engineering" 12-15 Jul 1997 , Novosibirsk |
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Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1998, Volume: 39, Number: 5, Pages: 696-701 Pages count : 6 | ||
Tags | ZIEGLER-NATTA CATALYSTS; HETEROGENEOUS CATALYSIS; OLEFINS | ||
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Abstract:
The experimental data are presented on effect of temperature on the catalyst activity and kinetics of ethylene polymerization over supported titanium-magnesium catalysts with different particle size and different concentrations electron-donor additive. The kinetic scheme of active site formation and monomer diffusion in a growing polymer particle developed earlier and modified in this work was used to estimate the rate constants and activation energies of the polymerization and the formation of active sites and unreactive by-products, which are inert titanium compounds.
Cite:
Skomorokhov V.B.
, Zakharov V.A.
, Kirillov V.A.
Determination of the Activation Energies of Ethylene Polymerization on Titanium-Magnesium Catalysts: Experiment and Mathematical Modeling
Kinetics and Catalysis. 1998. V.39. N5. P.696-701. WOS Scopus РИНЦ
Determination of the Activation Energies of Ethylene Polymerization on Titanium-Magnesium Catalysts: Experiment and Mathematical Modeling
Kinetics and Catalysis. 1998. V.39. N5. P.696-701. WOS Scopus РИНЦ
Original:
Скоморохов В.Б.
, Захаров В.А.
, Кириллов В.А.
Определение энергий активации при полимеризации этилена на титанмагниевых катализаторах, эксперимент и математическое моделирование
Кинетика и катализ. 1998. Т.39. №5. С.757-761. РИНЦ
Определение энергий активации при полимеризации этилена на титанмагниевых катализаторах, эксперимент и математическое моделирование
Кинетика и катализ. 1998. Т.39. №5. С.757-761. РИНЦ
Dates:
Submitted: | Jul 9, 1997 |
Identifiers:
Web of science | WOS:000076734300023 |
Scopus | 2-s2.0-0542400964 |
Elibrary | 13291335 |
Chemical Abstracts | 1998:740315 |
Chemical Abstracts (print) | 130:66842 |
Citing:
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