Kinetic Study of Catalytic Hydrogenation of Thiophene on a Palladium Sulfide Satalyst Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2002, Volume: 43, Number: 4, Pages: 528-535 Pages count : 8 DOI: 10.1023/A:1019831203005 | ||
Tags | Hydrogen; Sulfide; Activation Energy; Catalysis; Palladium | ||
Authors |
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Abstract:
The kinetics of thiophene hydrogenation on a palladium sulfide catalyst is studied at high hydrogen pressures. The reaction mainly occurs via the consecutive scheme: the reaction of thiophene with hydrogen results in the formation of tetrahydrothiophene, which partially decomposes under the action of hydrogen to yield butane and hydrogen sulfide. A kinetic model describing the reaction rates and the selectivity to tetrahydrothiophene at 0.2–3.0 MPa and 493–533 K is proposed. The rate constants and activation energies are determined. The effect of temperature and pressure on the maximal yield of tetrahydrothiophene is examined.
Cite:
Ermakova A.
, Mashkina A.V.
, Sakhaltueva L.G.
Kinetic Study of Catalytic Hydrogenation of Thiophene on a Palladium Sulfide Satalyst
Kinetics and Catalysis. 2002. V.43. N4. P.528-535. DOI: 10.1023/A:1019831203005 WOS Scopus РИНЦ
Kinetic Study of Catalytic Hydrogenation of Thiophene on a Palladium Sulfide Satalyst
Kinetics and Catalysis. 2002. V.43. N4. P.528-535. DOI: 10.1023/A:1019831203005 WOS Scopus РИНЦ
Original:
Ермакова А.
, Машкина А.В.
, Сахалтуева Л.Г.
Исследование кинетики каталитического гидрирования тиофена на сульфидпалладиевом катализаторе
Кинетика и катализ. 2002. Т.43. №4. С.572-579. РИНЦ
Исследование кинетики каталитического гидрирования тиофена на сульфидпалладиевом катализаторе
Кинетика и катализ. 2002. Т.43. №4. С.572-579. РИНЦ
Dates:
Submitted: | Jul 12, 2001 |
Published print: | Jul 1, 2002 |
Identifiers:
Web of science | WOS:000177849400012 |
Scopus | 2-s2.0-0038644394 |
Elibrary | 13396287 |
Chemical Abstracts | 2002:627509 |
Chemical Abstracts (print) | 138:55574 |
OpenAlex | W52444854 |