Sulfide Catalysts Supported on Al2O3: VI. Synthesis of Catalysts with the Use of Binuclear Molybdenum(V) Complexes with Sulfur-Containing Ligands Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2002, Volume: 43, Number: 4, Pages: 585-591 Pages count : 7 DOI: 10.1023/A:1019899623478 | ||
Tags | Immobilization;l Molybdenum; Thiophene; Active Component; Support Surface | ||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 01-03-32417 |
Abstract:
A new method was developed for the preparation of sulfide catalysts supported on aluminum oxide. The surface assembling of a direct precursor of the active component was used in this method. The method consists in the sequential immobilization of binuclear molybdenum complexes with S-containing ligands on the support surface followed by the immobilization of nickel (cobalt) compounds at the surface molybdenum complexes. The complexation and structure of the resulting complexes in solution and the structure of surface complexes were studied by 95Mo and 17O NMR, IR, and EXAFS spectroscopy. The surface assembling of a direct precursor of the active component of sulfide hydrodesulfurization catalysts was demonstrated using IR and EXAFS spectroscopy. The activity of the resulting catalysts in a model reaction of thiophene hydrogenolysis was comparable to the activity of sulfide catalysts of the metal complex origin and was much higher than the activity of commercial catalysts and catalysts prepared by impregnation.
Cite:
Serebrennikova Y.M.
, Fedotov M.A.
, Nikitenko S.G.
, Kochubey D.I.
, Startsev A.N.
Sulfide Catalysts Supported on Al2O3: VI. Synthesis of Catalysts with the Use of Binuclear Molybdenum(V) Complexes with Sulfur-Containing Ligands
Kinetics and Catalysis. 2002. V.43. N4. P.585-591. DOI: 10.1023/A:1019899623478 WOS Scopus РИНЦ
Sulfide Catalysts Supported on Al2O3: VI. Synthesis of Catalysts with the Use of Binuclear Molybdenum(V) Complexes with Sulfur-Containing Ligands
Kinetics and Catalysis. 2002. V.43. N4. P.585-591. DOI: 10.1023/A:1019899623478 WOS Scopus РИНЦ
Original:
Серебренникова Ю.М.
, Федотов М.А.
, Никитенко С.Г.
, Кочубей Д.И.
, Старцев А.Н.
Нанесенные на Al2O3 сульфидные катализаторы. VI. Синтез катализаторов с использованием биядерных комплексов молибдена(V) с S-содержащими лигандами
Кинетика и катализ. 2002. Т.43. №4. С.634-640. РИНЦ
Нанесенные на Al2O3 сульфидные катализаторы. VI. Синтез катализаторов с использованием биядерных комплексов молибдена(V) с S-содержащими лигандами
Кинетика и катализ. 2002. Т.43. №4. С.634-640. РИНЦ
Dates:
Submitted: | May 3, 2000 |
Published print: | Jul 1, 2002 |
Identifiers:
Web of science | WOS:000177849400021 |
Scopus | 2-s2.0-0037562468 |
Elibrary | 13397859 |
Chemical Abstracts | 2002:627518 |
Chemical Abstracts (print) | 138:26544 |
OpenAlex | W324325720 |