Reactions of Neutral and Charged Molybdenum Oxide Clusters with Low-Molecular-Weight Alcohols in a Gas Phase Studied by Ion Cyclotron Resonance Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2003, Volume: 44, Number: 4, Pages: 499-512 Pages count : 14 DOI: 10.1023/A:1025185816050 | ||
Tags | Alcohol; Methanol; Molybdenum; MoO2; Polycondensation | ||
Authors |
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Affiliations |
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Funding (2)
1 | International Science Foundation | RBG 000 |
2 | International Science Foundation | RBG 300 |
Abstract:
A set of oxygen-containing molybdenum oxide clusters MoxOy (x = 1–3; y = 1–9) was obtained with the use of a combination of a Knudsen cell and an ion trap cell. The reactions of positively charged clusters with C1–C4 alcohols were studied using ion cyclotron resonance. The formation of a number of organometallic ions, the products of initial insertion of molybdenum oxide ions into the C–O and C–H bonds of alcohols, and polycondensation products of methanol and ethanol were found. The reactions of neutral molybdenum oxide clusters MoxOy (x = 1–3; y = 1–9) with protonated C1–C4 alcohols and an ammonium ion were studied. The following limits of proton affinity (PA) were found for neutral oxygen-containing molybdenum clusters: (MoO) < 180, (Mo2O4, Mo2O5, and Mo3O8) = 188 ± 8, PA(MoO2) = 202 ± 5, PA(MoO3, Mo2O6, and Mo3O9) > 207 kcal/mol.
Cite:
Goncharov V.B.
Reactions of Neutral and Charged Molybdenum Oxide Clusters with Low-Molecular-Weight Alcohols in a Gas Phase Studied by Ion Cyclotron Resonance
Kinetics and Catalysis. 2003. V.44. N4. P.499-512. DOI: 10.1023/A:1025185816050 WOS Scopus РИНЦ
Reactions of Neutral and Charged Molybdenum Oxide Clusters with Low-Molecular-Weight Alcohols in a Gas Phase Studied by Ion Cyclotron Resonance
Kinetics and Catalysis. 2003. V.44. N4. P.499-512. DOI: 10.1023/A:1025185816050 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Гончаров В.Б.
Исследование реакций нейтральных и заряженных кластеров оксида молибдена низкомолекулярными спиртами в газовой фазе методом ионного циклотронного резонанса
Кинетика и катализ. 2003. Т.44. №4. С.548-562. РИНЦ
Исследование реакций нейтральных и заряженных кластеров оксида молибдена низкомолекулярными спиртами в газовой фазе методом ионного циклотронного резонанса
Кинетика и катализ. 2003. Т.44. №4. С.548-562. РИНЦ
Dates:
Submitted: | Dec 12, 2001 |
Published print: | Jul 1, 2003 |
Identifiers:
Web of science | WOS:000185169100009 |
Scopus | 2-s2.0-0041836167 |
Elibrary | 13428926 |
Chemical Abstracts | 2003:622289 |
Chemical Abstracts (print) | 140:41765 |
OpenAlex | W304535730 |