Kinetic Model of the Reaction of Methanol with Hydrogen Sulfide Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2004, Volume: 45, Number: 4, Pages: 522-529 Pages count : 8 DOI: 10.1023/B:KICA.0000038080.28824.f8 | ||
Tags | Hydrogen; Ether; Experimental Data; Methanol; Physical Chemistry | ||
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Abstract:
The kinetics of the reaction of methanol with hydrogen sulfide in the presence of an IKT-31 catalyst was experimentally studied. The experiments were performed in a fixed-bed flow reactor under the following conditions: T = 598-653 K,
P = 0.1-1.0 MPa, and P0 H2S/P0 Me =0.4-15.0. Rate equations were derived which describe the rates of formation of methanethiol as the main product and dimethyl sulfide and dimethyl ether as by-products. The rate constants and activation energies were found by the mathematical treatment of experimental data. The model proposed can be used for reactor design.
Cite:
Yermakova A.
, Mashkina A.V.
Kinetic Model of the Reaction of Methanol with Hydrogen Sulfide
Kinetics and Catalysis. 2004. V.45. N4. P.522-529. DOI: 10.1023/B:KICA.0000038080.28824.f8 WOS Scopus РИНЦ
Kinetic Model of the Reaction of Methanol with Hydrogen Sulfide
Kinetics and Catalysis. 2004. V.45. N4. P.522-529. DOI: 10.1023/B:KICA.0000038080.28824.f8 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Ермакова А.
, Машкина А.В.
Кинетическая модель реакции взаимодействия метанола с сероводородом
Кинетика и катализ. 2004. Т.45. №4. С.554-561. РИНЦ
Кинетическая модель реакции взаимодействия метанола с сероводородом
Кинетика и катализ. 2004. Т.45. №4. С.554-561. РИНЦ
Dates:
Submitted: | Nov 11, 2002 |
Published print: | Jul 1, 2004 |
Identifiers:
Web of science | WOS:000223776200010 |
Scopus | 2-s2.0-4344678267 |
Elibrary | 18243848 |
Chemical Abstracts | 2004:671522 |
Chemical Abstracts (print) | 141:410524 |
OpenAlex | W2015445194 |