Liquid-Phase Hydrodechlorination of Polychloroaromatic Compounds in the Presence of Pd-Promoted Nickel Catalysts Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||
---|---|---|---|
Output data | Year: 1998, Volume: 65, Number: 1, Pages: 177-183 Pages count : 7 DOI: 10.1007/BF02475332 | ||
Tags | Hydrodechlorination, Pd and Ni catalysts, Polychloroaromatic compounds | ||
Authors |
|
||
Affiliations |
|
Abstract:
Liquid phase hydrodechlorination of chlorobenzene, 1,2,4-trichlorobenzene, hexachlorobenzene, polychlorinated biphenyls in the ethanol-containing solution, on Me0/C (where Me0-Pd, Ni or bimetallic Ni−Pd; C-carbon material “Sibunit”) with H2 have been studied at 20–70°C and PH2=1–50 atm. Pd and Pd-promoted Ni catalysts exhibit the highest activity. Kinetic studies show hydrodechlorination of these compounds to be a consecutive reaction, which under the conditions described may produce less chlorinated compounds.
Cite:
Yakovlev V.A.
, Simagina V.I.
, Likholobov V.A.
Liquid-Phase Hydrodechlorination of Polychloroaromatic Compounds in the Presence of Pd-Promoted Nickel Catalysts
Reaction Kinetics and Catalysis Letters. 1998. V.65. N1. P.177-183. DOI: 10.1007/BF02475332 WOS Scopus РИНЦ
Liquid-Phase Hydrodechlorination of Polychloroaromatic Compounds in the Presence of Pd-Promoted Nickel Catalysts
Reaction Kinetics and Catalysis Letters. 1998. V.65. N1. P.177-183. DOI: 10.1007/BF02475332 WOS Scopus РИНЦ
Dates:
Submitted: | May 19, 1997 |
Accepted: | Jul 20, 1998 |
Published print: | Sep 1, 1998 |
Identifiers:
Web of science | WOS:000076925900025 |
Scopus | 2-s2.0-0000502817 |
Elibrary | 13293525 |
Chemical Abstracts | 1999:276046 |
Chemical Abstracts (print) | 130:342423 |
OpenAlex | W2002525039 |