Oxidation of Aniline with Solutions of Mo-V-Phosphoric Heteropolyacids ArticleGenre_short.SHORT_COMMUNICATION
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 2005, Volume: 54, Number: 6, Pages: 1532-1534 Pages count : 3 DOI: 10.1007/s11172-005-0442-x | ||||
Tags | 1,4-benzoquinone, Aniline, Catalytic oxidation, Heteropolyacids, Polyaniline | ||||
Authors |
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Affiliations |
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Funding (3)
1 | Russian Foundation for Basic Research | 03-03-32865 |
2 | Russian Foundation for Basic Research | 02-03-32280 |
3 | Council for Grants of the President of the Russian Federation | НШ-2030.2003.3 |
Abstract:
Mo—V-phosphoric heteropolyacids (HPA) can be used for aniline oxidation to polyaniline or 1,4-benzoquinone. At room temperature and the molar ratio HPA : aniline = 0.67, more than 95% substrate are oxidized to polyaniline. At 90–100 °C and HPA : aniline = 3, the substrate is quantitatively oxidized to 1,4-benzoquinone. Solutions of HPA are regenerated by oxygen in a separate step.
Cite:
Simonova M.V.
, Zhizhina E.G.
, Russkikh V.V.
, Matveev K.I.
Oxidation of Aniline with Solutions of Mo-V-Phosphoric Heteropolyacids
Russian Chemical Bulletin. 2005. V.54. N6. P.1532-1534. DOI: 10.1007/s11172-005-0442-x WOS Scopus РИНЦ
Oxidation of Aniline with Solutions of Mo-V-Phosphoric Heteropolyacids
Russian Chemical Bulletin. 2005. V.54. N6. P.1532-1534. DOI: 10.1007/s11172-005-0442-x WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Симонова М.В.
, Жижина Е.Г.
, Русских В.В.
, Матвеев К.И.
Окисление анилина растворами Мо-V-фосфорных гетерополикислот
Известия Академии наук. Серия химическая. 2005. №6. С.1488-1491. РИНЦ
Окисление анилина растворами Мо-V-фосфорных гетерополикислот
Известия Академии наук. Серия химическая. 2005. №6. С.1488-1491. РИНЦ
Dates:
Submitted: | Jul 19, 2004 |
Accepted: | Mar 15, 2005 |
Published print: | Jun 1, 2005 |
Identifiers:
Web of science | WOS:000234157200032 |
Scopus | 2-s2.0-28644437750 |
Elibrary | 13483482 |
Chemical Abstracts | 2005:1281622 |
Chemical Abstracts (print) | 145:167674 |
OpenAlex | W2950705631 |