A Study of Complexation of Chloral Hydrate with Heteropoly Anions Having Various Structures Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 2001, Volume: 50, Number: 9, Pages: 1529-1532 Pages count : 4 DOI: 10.1023/A:1013009829272 | ||
Tags | 1H NMR, Acidity, Basicity, Heteropoly acids | ||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 00-15-97447 |
Abstract:
1H NMR was applied to study the interaction of chloral hydrate in deuterionitrobenzene solution with tetrabutylammonium salts of the heteropoly acids (HPA) belonging to five structural types: Keggin (H3PW12O40, H3PMo12O40, H4SiW12O40), Dawson (α-H6P2W18O62, α-H6P2Mo18O62, α-H4S2Mo18O62), H6P2W21O71(H2O)3, H6As2W21O69(H2O), and H21B3W39O132. The surface of the HPA anions is nonuniform in acid-base properties. A general rule for all HPA was found, namely, that the HPA acidity increases with a decrease in the specific anion charge (per W or Mo atom).
Cite:
Maksimov G.M.
, Timofeeva M.N.
, Likholobov V.A.
A Study of Complexation of Chloral Hydrate with Heteropoly Anions Having Various Structures
Russian Chemical Bulletin. 2001. V.50. N9. P.1529-1532. DOI: 10.1023/A:1013009829272 WOS Scopus РИНЦ
A Study of Complexation of Chloral Hydrate with Heteropoly Anions Having Various Structures
Russian Chemical Bulletin. 2001. V.50. N9. P.1529-1532. DOI: 10.1023/A:1013009829272 WOS Scopus РИНЦ
Original:
Максимов Г.М.
, Тимофеева М.Н.
, Лихолобов В.А.
Комплексообразование хлоральгидрата с гетерополианионами различных структур
Известия Академии наук. Серия химическая. 2001. №9. С.1455-1458. РИНЦ
Комплексообразование хлоральгидрата с гетерополианионами различных структур
Известия Академии наук. Серия химическая. 2001. №9. С.1455-1458. РИНЦ
Dates:
Submitted: | Jun 26, 2000 |
Published print: | Sep 1, 2001 |
Identifiers:
Web of science | WOS:000173526100007 |
Scopus | 2-s2.0-0035528221 |
Elibrary | 13386534 |
Chemical Abstracts | 2002:88128 |
Chemical Abstracts (print) | 136:318340 |
OpenAlex | W188030347 |