Nuclear Magnetic Resonance of Donor Atoms as a Tool for Determination of the Structure of Platinum Metal Complexes in Solutions Review
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 2003, Volume: 52, Number: 4, Pages: 781-794 Pages count : 14 DOI: 10.1023/A:1024465718716 | ||
Tags | 13C NMR spectroscopy, 14N NMR spectroscopy, 17O NMR spectroscopy, 19F NMR spectroscopy, 1H NMR spectroscopy, 31P NMR spectroscopy, Complexes, NMR of donor atoms, Platinum metals, Structure | ||
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Abstract:
Data on the NMR spectroscopy of C, N, O, Si, P, and Sn donor atoms of platinum metal complexes in solutions are surveyed. The chemical shift of a donor atom mainly depends on the ligand in the trans-position (due to the trans-effect). The chemical shift of a donor atom on a particular coordinate of the complex (coordinate shift, CSh) is an attribute of this coordinate and can be used to identify such a coordinate in platinum metal complexes and to determine the structures of complexes. Based on the known data, CSh diagrams were composed for 1H, 13C, 14N, 17O, 19F, 31P, and 119Sn. Examples of using the CShs for determining the structures of platinum metal complexes in solutions are presented.
Cite:
Fedotov M.A.
Nuclear Magnetic Resonance of Donor Atoms as a Tool for Determination of the Structure of Platinum Metal Complexes in Solutions
Russian Chemical Bulletin. 2003. V.52. N4. P.781-794. DOI: 10.1023/A:1024465718716 WOS Scopus РИНЦ
Nuclear Magnetic Resonance of Donor Atoms as a Tool for Determination of the Structure of Platinum Metal Complexes in Solutions
Russian Chemical Bulletin. 2003. V.52. N4. P.781-794. DOI: 10.1023/A:1024465718716 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Федотов М.А.
Ядерный магнитный резонанс донорных атомов как инструмент для определения строения комплексов платиновых металлов в растворах
Известия Академии наук. Серия химическая. 2003. №4. С.743-755. РИНЦ
Ядерный магнитный резонанс донорных атомов как инструмент для определения строения комплексов платиновых металлов в растворах
Известия Академии наук. Серия химическая. 2003. №4. С.743-755. РИНЦ
Dates:
Submitted: | May 7, 2002 |
Accepted: | Dec 25, 2002 |
Published print: | Apr 1, 2003 |
Identifiers:
Web of science | WOS:000184376900001 |
Scopus | 2-s2.0-0038421223 |
Elibrary | 13442969 |
Chemical Abstracts | 2003:493248 |
Chemical Abstracts (print) | 139:344490 |
OpenAlex | W267445278 |