The Extraction of Heterometal Complexes of Ruthenium(II) with Trioctylphosphine Oxide from Nitrate Solutions Full article
Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
||||
---|---|---|---|---|---|
Output data | Year: 2003, Volume: 48, Number: 6, Pages: 923-930 Pages count : 8 | ||||
Tags | nitrate; ruthenium complex; trioctylphosphine oxide | ||||
Authors |
|
||||
Affiliations |
|
Abstract:
Synergic extraction of [RuNO(NO2)(4)OH](2-) with trioctylphosphine oxide in the presence of nonferrous metals (M) is studied. The extraction is due to the formation of heterometal Ru/M complexes in which M2+ is coordinated to ruthenium via OH and NO2 oxygens and the extractant is coordinated to M2+. The complexes have a tetrahedral or octahedral configuration. The extraction constants of these complexes have the order (Zn2+-Cu2+-Co2+-Ni2+) that follows the Irving-Williams stability row.
Cite:
Torgov V.G.
, Shulʹman R.S.
, Stoyanov E.S.
, Us T.V.
, Korda T.M.
The Extraction of Heterometal Complexes of Ruthenium(II) with Trioctylphosphine Oxide from Nitrate Solutions
Russian Journal of Inorganic Chemistry. 2003. V.48. N6. P.923-930. WOS Scopus РИНЦ
The Extraction of Heterometal Complexes of Ruthenium(II) with Trioctylphosphine Oxide from Nitrate Solutions
Russian Journal of Inorganic Chemistry. 2003. V.48. N6. P.923-930. WOS Scopus РИНЦ
Original:
Торгов В.Г.
, Шульман Р.С.
, Стоянов Е.С.
, Ус Т.В.
, Корда Т.М.
Экстракция гетерометаллических комплексов рутения(II) триоктилфосфиноксидом из нитратных растворов
Журнал неорганической химии. 2003. Т.48. №6. С.1024-1031. РИНЦ
Экстракция гетерометаллических комплексов рутения(II) триоктилфосфиноксидом из нитратных растворов
Журнал неорганической химии. 2003. Т.48. №6. С.1024-1031. РИНЦ
Dates:
Submitted: | Oct 21, 2002 |
Published print: | Jun 1, 2003 |
Identifiers:
Web of science | WOS:000183763600020 |
Scopus | 2-s2.0-8744249176 |
Elibrary | 13433096 |