The Determination of Proton Affinity for Oxygen-Containing Molybdenum Clusters by the Method of Ion Cyclotron resonance Full article
Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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Output data | Year: 2000, Volume: 74, Number: 5, Pages: 791-793 Pages count : 3 | ||
Tags | GAS-PHASE; MOLECULES | ||
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Abstract:
Several oxygen-containing molybdenum clusters MoxOy (x = 1-3, y = 1-9) were prepared in a Knudsen cell combined with an ion trap. The reactions of the clusters with C-1-C-4 protonated alcohols and the ammonium ion were studied by ion cyclotron resonance. The upper and lower proton affinity limits determined for the neutral oxygen-containing molybdenum clusters equaled PA(MoO) < 180, PA(Mo2O4, Mo2O5, Mo3O8) = 188 +/- 8, PA(MoO2)= 202 +/- 5, and PA(MoO3, Mo2O6, Mo3O9) > 207 kcal/mol.
Cite:
Goncharov V.B.
, Fialko E.F.
The Determination of Proton Affinity for Oxygen-Containing Molybdenum Clusters by the Method of Ion Cyclotron resonance
Russian Journal of Physical Chemistry A. 2000. V.74. N5. P.791-793. WOS Scopus РИНЦ
The Determination of Proton Affinity for Oxygen-Containing Molybdenum Clusters by the Method of Ion Cyclotron resonance
Russian Journal of Physical Chemistry A. 2000. V.74. N5. P.791-793. WOS Scopus РИНЦ
Original:
Гончаров В.Б.
, Фиалко Е.Ф.
Определение сродства к протону кислородсодержащих кластеров молибдена методом ионно-циклотронного резонанса
Журнал физической химии. 2000. Т.74. №5. С.896-898. Scopus РИНЦ
Определение сродства к протону кислородсодержащих кластеров молибдена методом ионно-циклотронного резонанса
Журнал физической химии. 2000. Т.74. №5. С.896-898. Scopus РИНЦ
Dates:
Submitted: | Mar 3, 1999 |
Published print: | May 1, 2000 |
Identifiers:
Web of science | WOS:000087127700023 |
Scopus | 2-s2.0-0034341935 |
Elibrary | 13345561 |