Analysis of a Two-Phase Perfectly Mixed Reactor under the Condition of a Phase Equilibrium Full article
Journal |
Theoretical Foundations of Chemical Engineering
ISSN: 0040-5795 , E-ISSN: 1608-3431 |
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Output data | Year: 2001, Volume: 35, Number: 5, Pages: 486-493 Pages count : 8 DOI: 10.1023/A:1012330205085 | ||
Tags | Phase Equilibrium; Thermodynamic Equilibrium; Efficient Algorithm; Flow Reactor; Ideal System | ||
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Abstract:
A mathematical model is formulated for a gas–liquid perfectly mixed flow reactor under the condition that the two-phase flow at the reactor outlet is at thermodynamic equilibrium. The phase equilibrium is calculated using the Redlich–Kwong–Soave equation of state. The set of nonlinear algebraic equations of the model is numerically solved by the efficient algorithm of the homotopy method. The steady-state modes of reactor operation are analyzed for liquid-phase benzene hydrogenation. It is shown that, under isothermal isobaric conditions, there can be a multiplicity of steady-state solutions, which is, on the one hand, due to the nonlinearity of the kinetic law and, on the other, due to the deviation of the properties of the reaction mixture from the properties of an ideal system. The stability of the steady-state solutions is analyzed, and the causes of the multiplicity and instability are explained.
Cite:
Ermakova A.
, Gudkov M.V.
, Anikeev V.I.
Analysis of a Two-Phase Perfectly Mixed Reactor under the Condition of a Phase Equilibrium
Theoretical Foundations of Chemical Engineering. 2001. V.35. N5. P.486-493. DOI: 10.1023/A:1012330205085 WOS Scopus РИНЦ
Analysis of a Two-Phase Perfectly Mixed Reactor under the Condition of a Phase Equilibrium
Theoretical Foundations of Chemical Engineering. 2001. V.35. N5. P.486-493. DOI: 10.1023/A:1012330205085 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Ермакова А.
, Гудков М.В.
, Аникеев В.И.
Анализ реактора идеального перемешивания с двухфазным потоком в условиях фазового равновесия
Теоретические основы химической технологии. 2001. Т.35. №5. С.514-522. Scopus РИНЦ
Анализ реактора идеального перемешивания с двухфазным потоком в условиях фазового равновесия
Теоретические основы химической технологии. 2001. Т.35. №5. С.514-522. Scopus РИНЦ
Dates:
Submitted: | Dec 15, 1999 |
Published print: | Sep 1, 2001 |
Identifiers:
Web of science | WOS:000171839100011 |
Scopus | 2-s2.0-0035647565 |
Elibrary | 18255626 |
Chemical Abstracts | 2001:811373 |
Chemical Abstracts (print) | 136:21440 |
OpenAlex | W115496218 |