Kinetic Modelling of One-Pot Myrtenol Amination over Au/ZrO2 Catalyst Full article
Conference |
XX International Conference on Chemical Reactors 03-07 Dec 2012 , Luxemburg |
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Journal |
Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212 |
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Output data | Year: 2014, Volume: 238, Pages: 164-171 Pages count : 8 DOI: 10.1016/j.cej.2013.09.007 | ||||||
Tags | Amination, Gold nanoparticles, Kinetics, Modeling, Myrtenol, One-pot | ||||||
Authors |
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Affiliations |
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Funding (3)
1 |
National Autonomous University of Mexico National Council of Science and Technology |
179619 |
2 | National Autonomous University of Mexico | 203813 |
3 | Russian Foundation for Basic Research | 12-03-31623 |
Abstract:
A perspective environmentally-benign one-pot approach to the synthesis of complicated amines by alcohol amination was investigated in this work by mathematical modeling using myrtenol, which represents a natural terpene alcohol, and aniline as model substrates. The reaction was studied in the presence of Au/ZrO2 catalyst in the temperature range 413–453 K under kinetic control. Mechanistic model taking into account catalyst deactivation was developed from a proposed reaction mechanism and corresponding kinetic equations were derived. Kinetic model was compared with experimental data through numerical data fitting showing good correspondence.
Cite:
Demidova Y.S.
, Simakova I.L.
, Warna J.
, Simakov A.
, Murzin D.Y.
Kinetic Modelling of One-Pot Myrtenol Amination over Au/ZrO2 Catalyst
Chemical Engineering Journal. 2014. V.238. P.164-171. DOI: 10.1016/j.cej.2013.09.007 WOS Scopus РИНЦ
Kinetic Modelling of One-Pot Myrtenol Amination over Au/ZrO2 Catalyst
Chemical Engineering Journal. 2014. V.238. P.164-171. DOI: 10.1016/j.cej.2013.09.007 WOS Scopus РИНЦ
Dates:
Published online: | Sep 7, 2013 |
Published print: | Feb 15, 2014 |
Identifiers:
Web of science | WOS:000331431500021 |
Scopus | 2-s2.0-84897086356 |
Elibrary | 21869620 |
Chemical Abstracts | 2013:1537449 |
Chemical Abstracts (print) | 160:87441 |
OpenAlex | W2040623909 |