Catalytic Oxidation of Octene-1 in the Presence of Palladium(II) Salts and Heteropolyacids Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1981, Volume: 16, Number: 4, Pages: 383-386 Pages count : 4 DOI: 10.1007/BF02066595 | ||||
Tags | Oxidation; Physical Chemistry; Activation Energy; Catalysis; Palladium | ||||
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Abstract:
In the presence of the catalytic system (PdSO4+HPA), where HPA=H9PMo6V6O40, octene-1 is found to be selectively (95%) oxidized to octanone-2. The optimum concentration ratio for catalyst stability is [HPA]:[PdSO4]=30–40. The substitution of PdCl2 for PdSO4 leads to the formation of all three isomeric octanones without decrease of the overall selectivity. Effective rate constants and the apparent activation energy have been determined in the temperature range from 60 to
80 °C.
Cite:
Čihova M.
, Hrušovsky M.
, Voitko J.
, Matveev K.I.
Catalytic Oxidation of Octene-1 in the Presence of Palladium(II) Salts and Heteropolyacids
Reaction Kinetics and Catalysis Letters. 1981. V.16. N4. P.383-386. DOI: 10.1007/BF02066595 WOS Scopus РИНЦ
Catalytic Oxidation of Octene-1 in the Presence of Palladium(II) Salts and Heteropolyacids
Reaction Kinetics and Catalysis Letters. 1981. V.16. N4. P.383-386. DOI: 10.1007/BF02066595 WOS Scopus РИНЦ
Dates:
Submitted: | Oct 17, 1980 |
Accepted: | Dec 19, 1980 |
Published print: | Jun 1, 1981 |
Identifiers:
Web of science | WOS:A1981MA22500016 |
Scopus | 2-s2.0-0042700893 |
Elibrary | 31106834 |
Chemical Abstracts | 1981:568153 |
Chemical Abstracts (print) | 95:168153 |
OpenAlex | W1996573210 |