Photolysis of Alkylperoxy Radicals Frozen out from the Gas Phase Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1986, Volume: 32, Number: 2, Pages: 429-434 Pages count : 6 DOI: 10.1007/BF02068347 | ||
Tags | Physical Chemistry; Catalysis; Alkyl Radical; Photolysis; Decomposition Reaction | ||
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Abstract:
Photolysis of alkylperoxy radicals with λ≦250 nm light has been studied and proposed for investigation of heterogeneous-homogeneous reactions by freezing out radicals from the gas phase and their ESR identification. Using amine decomposition reaction in the presence of O2 as an example, we have shown that photodissociation of frozen peroxy radicals can be used to reduce the structure of initial alkyl radicals.
Cite:
Pak S.N.
, Yermolayev V.K.
, Ismagilov Z.R.
Photolysis of Alkylperoxy Radicals Frozen out from the Gas Phase
Reaction Kinetics and Catalysis Letters. 1986. V.32. N2. P.429-434. DOI: 10.1007/BF02068347 WOS Scopus РИНЦ
Photolysis of Alkylperoxy Radicals Frozen out from the Gas Phase
Reaction Kinetics and Catalysis Letters. 1986. V.32. N2. P.429-434. DOI: 10.1007/BF02068347 WOS Scopus РИНЦ
Dates:
Submitted: | Oct 18, 1985 |
Accepted: | Jan 8, 1986 |
Published print: | Sep 1, 1986 |
Identifiers:
Web of science | WOS:A1986H257200029 |
Scopus | 2-s2.0-27144543243 |
Elibrary | 31121548 |
Chemical Abstracts | 1987:224250 |
Chemical Abstracts (print) | 106:224250 |
OpenAlex | W1996825933 |