Redistribution Kinetics of Isotope Molecules Due to Reversible Bimolecular Reactions with Several Atomic Channels
Reaction Kinetics and Catalysis Letters
, E-ISSN: 1588-2837
Institute of Catalysis, Novosibirsk 630090, USSR
Isotope kinetic equations for reversible bimolecular reactions describe the rearrangement of atoms in activated complexes. It has been established from the model reaction CH4+H⇆CH3+H2 that the isotopic homoexchange of methane via two atomic channels is given by one set of equations with different sets of parameters.