Kinetics of Decomposition of Isopropylbenzene Hydroperoxide Catalyzed by Dodecamolybdophosphoric acid Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1977, Volume: 7, Number: 3, Pages: 291-296 Pages count : 6 DOI: 10.1007/BF02062458 | ||||
Tags | Physical Chemistry; Acetone; Activation Energy; Catalysis; Hydroperoxide | ||||
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Abstract:
Using the NMR method, the kinetics of decomposition of isopropylbenzene hydroperoxide catalyzed by dodecamolybdophosphoric acid has been investigated in acetone at 22–50°C. The reaction is first order with respect to both the hydroperoxide and the catalyst, the activation energy is 14 kcal/mol. The data obtained are in agreement with the reaction mechanism suggested by Kharasch /1/.
Cite:
Kozhevnikov I.V.
, Mastikhin V.M.
, Matveev K.I.
, Kirichenko G.N.
, Churkin Y.V.
, Glazunova V.I.
Kinetics of Decomposition of Isopropylbenzene Hydroperoxide Catalyzed by Dodecamolybdophosphoric acid
Reaction Kinetics and Catalysis Letters. 1977. V.7. N3. P.291-296. DOI: 10.1007/BF02062458 WOS Scopus РИНЦ
Kinetics of Decomposition of Isopropylbenzene Hydroperoxide Catalyzed by Dodecamolybdophosphoric acid
Reaction Kinetics and Catalysis Letters. 1977. V.7. N3. P.291-296. DOI: 10.1007/BF02062458 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 3, 1977 |
Accepted: | Feb 23, 1977 |
Published print: | Oct 1, 1977 |
Identifiers:
Web of science | WOS:A1977DZ87700009 |
Scopus | 2-s2.0-5844378297 |
Elibrary | 30922049 |
Chemical Abstracts | 1978:21819 |
Chemical Abstracts (print) | 88:21819 |
OpenAlex | W1984789885 |