Acetoxylation of Olefins Catalyzed by a Palladium(II)-Heteropolyacid System Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1977, Volume: 7, Number: 3, Pages: 297-302 Pages count : 6 DOI: 10.1007/BF02062459 | ||
Tags | Oxidation; Oxygen; Acetate; Acetaldehyde; Physical Chemistry | ||
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Abstract:
The catalytic acetoxylation of ethylene and propylene occurs under the action of oxygen in the presence of
Pd(II)+HPA-6, where HPA-6 is the heteropolyacid H9PMo6V6O40. In addition to the products of acetoxylation (alkenyl and allyl acetates), oxidation products (acetaldehyde and acetone) are also formed. The selectivity of acetoxylation increases upon the addition of NaOAc.
Показана возможность каталитического ацетоксилирования олефинов — этилена и пропилена — под действием кислорода в присутствии катализатора Pd(II)+ГПК-6, где ГПК-6 фосфорномолибдованадиевая гетерополикислота H9PMo6V6O40. Наряду с продуктами ацетоксилирования (алкенил- и аллилацетаты) образуются продукты окисления — ацетальдегид и ацетон. Селективность реакции ацетоксилирования возрастает при добавках NaOAc.
Cite:
Kozhevnikov I.V.
, Tarabanʹko V.E.
, Matveev K.I.
, Vardanyan V.D.
Acetoxylation of Olefins Catalyzed by a Palladium(II)-Heteropolyacid System
Reaction Kinetics and Catalysis Letters. 1977. V.7. N3. P.297-302. DOI: 10.1007/BF02062459 WOS Scopus РИНЦ
Acetoxylation of Olefins Catalyzed by a Palladium(II)-Heteropolyacid System
Reaction Kinetics and Catalysis Letters. 1977. V.7. N3. P.297-302. DOI: 10.1007/BF02062459 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 3, 1977 |
Accepted: | Feb 23, 1977 |
Published print: | Oct 1, 1977 |
Identifiers:
Web of science | WOS:A1977DZ87700010 |
Scopus | 2-s2.0-34250288285 |
Elibrary | 30908245 |
Chemical Abstracts | 1978:22032 |
Chemical Abstracts (print) | 88:22032 |
OpenAlex | W1975962668 |