Mechanochemical Synthesis of Solid Solutions Based on ZrO2 and Their Electrical Conductivity Full article
Conference |
Structural Chemistry of Partially Ordered Systems, Nanoparticles and Nanocomposites: Topical Meeting of the European Ceramic Society 27-29 Jun 2006 , Saint-Petersburg |
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Journal |
Glass Physics and Chemistry
ISSN: 1087-6596 , E-ISSN: 1608-313X |
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Output data | Year: 2007, Volume: 33, Number: 4, Pages: 394-401 Pages count : 8 DOI: 10.1134/S1087659607040141 | ||||
Tags | Ceramic Material; Solid Electrolyte; Solid State Ionic; Monoclinic Phase; Glass Physic | ||||
Authors |
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Affiliations |
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Funding (4)
1 | Siberian Branch of the Russian Academy of Sciences | 95 |
2 | International Science and Technology Center | 3234 |
3 | Russian Foundation for Basic Research | 06-03-32131 |
4 | Council for Grants of the President of the Russian Federation | НШ-4505.2006.3 |
Abstract:
Zirconia-and scandia-based complex solid solutions predominantly with a monoclinic structure are prepared by mechanochemical synthesis. The dense ceramic materials, which, for the most part, have a cubic structure with grain sizes of 250–400 nm and possess good mechanical properties, are produced by sintering submicron fractions of the powders under relatively mild conditions at temperatures of 1633–1653 K. It is revealed that the powders are characterized by nanostructuring due to the complex composition and the chemical inhomogeneity. This nanostructuring is partially retained upon rapid sintering of the ceramic powders. The nanostructured ceramic materials possess a high low-temperature conductivity, which decreases after annealing. Unlike conventional ceramic materials, the nanostructured ceramic materials have identical activation energies for bulk and grain-boundary electrical conduction. The high-temperature electrical conductivity of the nanostructured ceramic materials is rather low because of the small grain sizes and impurities of the monoclinic phase.
Cite:
Zyryanov V.V.
, Uvarov N.F.
, Sadykov V.A.
Mechanochemical Synthesis of Solid Solutions Based on ZrO2 and Their Electrical Conductivity
Glass Physics and Chemistry. 2007. V.33. N4. P.394-401. DOI: 10.1134/S1087659607040141 WOS Scopus РИНЦ
Mechanochemical Synthesis of Solid Solutions Based on ZrO2 and Their Electrical Conductivity
Glass Physics and Chemistry. 2007. V.33. N4. P.394-401. DOI: 10.1134/S1087659607040141 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Зырянов В.В.
, Уваров Н.Ф.
, Садыков В.А.
Механохимический синтез твердых растворов на основе ZrO2 и их проводимость
Физика и химия стекла. 2007. Т.33. №4. С.546-555. РИНЦ
Механохимический синтез твердых растворов на основе ZrO2 и их проводимость
Физика и химия стекла. 2007. Т.33. №4. С.546-555. РИНЦ
Dates:
Published print: | Aug 1, 2007 |
Identifiers:
Web of science | WOS:000249259800014 |
Scopus | 2-s2.0-34548457784 |
Elibrary | 13543840 |
Chemical Abstracts | 2007:986022 |
Chemical Abstracts (print) | 148:500983 |
OpenAlex | W1982745840 |