Styrene–Acrylate Copolymer Plastisols with Stable Colloidal Properties Full article
Journal |
Polymer Science Series A
ISSN: 0965-545X , E-ISSN: 1555-6107 |
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Output data | Year: 2007, Volume: 49, Number: 10, Pages: 1086-1092 Pages count : 7 DOI: 10.1134/S0965545X07100045 | ||
Tags | Styrene; Phthalate; Polymer Science Series; Polymer Particle; Monomer Mixture | ||
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Abstract:
Methods for the synthesis of emulsion-polymerized styrene-methyl methacrylate-methacrylic acid copolymers with different compositions and structures are proposed. Stable plastisols are obtained from these copolymers and phthalate plasticizers. Factors that affect the colloidal stability and rheological properties of the plastisols were studied. These are the polymer particle size, the type of surfactants used in emulsion copolymerization, the distribution of methacrylic acid units over the latex particle volume (uniform or gradient, with concentration rising from the particle center to periphery), the degree of carboxyl group neutralization with a base, and the nature of plasticizers. The plastisols obtained are characterized by a pseudoplastic flow. However, as the degree of carboxyl group neutralization in the copolymers is increased, the rheological properties of the plastisols approach those of Newtonian liquids.
Cite:
Pavlyuchenko V.N.
, Primachenko O.N.
, Ivanchev S.S.
Styrene–Acrylate Copolymer Plastisols with Stable Colloidal Properties
Polymer Science Series A. 2007. V.49. N10. P.1086-1092. DOI: 10.1134/S0965545X07100045 WOS Scopus РИНЦ
Styrene–Acrylate Copolymer Plastisols with Stable Colloidal Properties
Polymer Science Series A. 2007. V.49. N10. P.1086-1092. DOI: 10.1134/S0965545X07100045 WOS Scopus РИНЦ
Original:
Павлюченко В.Н.
, Примаченко О.Н.
, Иванчев С.С.
Коллоидно-устойчивые пластизоли на основе эмульсионных стирол-акрилатных сополимеров
Высокомолекулярные соединения. Серия А. 2007. Т.49. №10. С.1774-1782. РИНЦ
Коллоидно-устойчивые пластизоли на основе эмульсионных стирол-акрилатных сополимеров
Высокомолекулярные соединения. Серия А. 2007. Т.49. №10. С.1774-1782. РИНЦ
Dates:
Submitted: | Oct 12, 2006 |
Published print: | Oct 1, 2007 |
Identifiers:
Web of science | WOS:000250582800004 |
Scopus | 2-s2.0-35648979588 |
Elibrary | 13551427 |
OpenAlex | W1986562487 |
Citing:
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