The State of Al(III) in Alcohol Solutions of Aluminum Alkoxide as Probed by 27Al and 13C NMR and Small-Angle X-Ray Scattering Full article
Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
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Output data | Year: 2008, Volume: 53, Number: 10, Pages: 1621-1627 Pages count : 7 DOI: 10.1134/S0036023608100161 | ||
Tags | Aluminum Atom; Polynuclear Complex; Aluminum Species; SAXS Data; SAXS Pattern | ||
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Abstract:
Solutions of aluminum alkoxides obtained by interaction of aluminum metal with methyl, ethyl,
and isopropyl alcohols were studied by 27Al and 13C NMR and small-angle X-ray scattering. Alkoxides with a
tetrahedral environment of aluminum prevail in methanol solutions, and those with an octahedral environment
of aluminum predominate in ethanol solutions. In isopropyl alcohol at 293 K, polynuclear alkoxides with tetrahedral,
octahedral, and pentacoordinated aluminum environments coexist. The structure of polynuclear complexes
was refined by comparison of their calculated dimensions with small-angle X-ray scattering data.
Cite:
Fedotov M.A.
, Molchanov V.V.
, Zotov R.
, Tuzikov F.V.
The State of Al(III) in Alcohol Solutions of Aluminum Alkoxide as Probed by 27Al and 13C NMR and Small-Angle X-Ray Scattering
Russian Journal of Inorganic Chemistry. 2008. V.53. N10. P.1621-1627. DOI: 10.1134/S0036023608100161 WOS Scopus РИНЦ
The State of Al(III) in Alcohol Solutions of Aluminum Alkoxide as Probed by 27Al and 13C NMR and Small-Angle X-Ray Scattering
Russian Journal of Inorganic Chemistry. 2008. V.53. N10. P.1621-1627. DOI: 10.1134/S0036023608100161 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Федотов М.А.
, Молчанов В.В.
, Зотов Р.А.
, Тузиков Ф.В.
О состоянии Al(III) в спиртовых растворах алкоксидов алюминия по данным ЯМР (27Al, 13C) и малоуглового рентгеновского рассеяния
Журнал неорганической химии. 2008. Т.53. №10. С.1735-1741. РИНЦ
О состоянии Al(III) в спиртовых растворах алкоксидов алюминия по данным ЯМР (27Al, 13C) и малоуглового рентгеновского рассеяния
Журнал неорганической химии. 2008. Т.53. №10. С.1735-1741. РИНЦ
Dates:
Submitted: | Apr 24, 2007 |
Published print: | Oct 1, 2008 |
Published online: | Oct 14, 2008 |
Identifiers:
Web of science | WOS:000260018900016 |
Scopus | 2-s2.0-54149096523 |
Elibrary | 13589906 |
OpenAlex | W2035002169 |