Interaction of Arsenite Ions with Molybdate in Aqueous Solution Full article
Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
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Output data | Year: 2008, Volume: 53, Number: 4, Pages: 649-654 Pages count : 6 DOI: 10.1134/S0036023608040281 | ||||
Tags | Arsenic; Arsenite; Sodium Arsenite; Sodium Molybdate; Heteropoly Compound | ||||
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Abstract:
Interaction of arsenite ions with molybdate ions in aqueous HClO4 at pH of 3–5 were studied using
spectrophotometry. A heteropoly anion (HPA) with the AsMo4 stoichiometry was revealed. Elemental analysis,
X-ray photoelectron spectroscopy, and IR spectroscopy were used to characterize the composition and structure
of the cesium salt of As(III)–Mo(VI) HPA precipitated from solution. The comparison of the IR spectra of
cesium salts of the synthesized HPA and dimethylarsenite HPA (CH3)2AsMo4O15H2–, whose structure is
known, implies that AsMo4 has a similar structure, where the As group is linked by four connected
molybdenum octahedra (Mo4O12)O2–.
Cite:
Koshcheeva O.S.
, Kuznetsova L.I.
, Shuvaeva O.V.
Interaction of Arsenite Ions with Molybdate in Aqueous Solution
Russian Journal of Inorganic Chemistry. 2008. V.53. N4. P.649-654. DOI: 10.1134/S0036023608040281 WOS Scopus РИНЦ
Interaction of Arsenite Ions with Molybdate in Aqueous Solution
Russian Journal of Inorganic Chemistry. 2008. V.53. N4. P.649-654. DOI: 10.1134/S0036023608040281 WOS Scopus РИНЦ
Original:
Кощеева О.С.
, Кузнецова Л.И.
, Шуваева О.В.
Взаимодействие арсенит-ионов с молибдатом в водном растворе
Журнал неорганической химии. 2008. Т.53. №4. С.705-710. РИНЦ
Взаимодействие арсенит-ионов с молибдатом в водном растворе
Журнал неорганической химии. 2008. Т.53. №4. С.705-710. РИНЦ
Dates:
Submitted: | Mar 1, 2007 |
Published print: | Apr 1, 2008 |
Published online: | May 6, 2008 |
Identifiers:
Web of science | WOS:000255630300028 |
Scopus | 2-s2.0-43149093749 |
Elibrary | 13583316 |
OpenAlex | W2073848497 |
Citing:
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