On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics Full article
Journal |
Кинетика и катализ
ISSN: 0453-8811 |
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Output data | Year: 2010, Volume: 51, Number: 6, Pages: 855-858 Pages count : 4 | ||||
Authors |
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Affiliations |
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Funding (2)
1 | The Ministry of Education and Science of the Russian Federation | 02.740.11.5178 |
2 | Suomen Akatemia |
Abstract:
Quantitative description for turnover frequency dependence on the metal cluster size for a two-step catalytic cycle was performed based on a thermodynamic approach, which accounts for changes of the chemical potential upon adsorption depending on the metal cluster size. Such analysis revealed a possibility for turnover frequency to exhibit a maximum. A very good correspondence between calculated and experimental data in hydrogenation and decarboxylation reactions over palladium was achieved.
Cite:
Murzin D.Y.
, Simakova I.L.
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Кинетика и катализ. 2010. V.51. N6. P.855-858. RSCI РИНЦ
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Кинетика и катализ. 2010. V.51. N6. P.855-858. RSCI РИНЦ
ArticleLinkType.ORIGINAL_TO_TRANSLATED:
Murzin D.Y.
, Simakova I.L.
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Kinetics and Catalysis. 2010. V.51. N6. P.828-831. DOI: 10.1134/S002315841006008X WOS Scopus РИНЦ
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Kinetics and Catalysis. 2010. V.51. N6. P.828-831. DOI: 10.1134/S002315841006008X WOS Scopus РИНЦ
Dates:
Submitted: | Nov 13, 2009 |
Identifiers:
RSCI | RSCI:15524764 |
Elibrary | 15524764 |
publication.block.citing_info:
БД | Цитирований |
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Elibrary | 1 |