A Multinuclear Magnetic Resonance Study of Transformations of Ruthenium(II) Nitrosyl Chloride Complexes in Aqueous Solutions Full article
Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
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Output data | Year: 2013, Volume: 58, Number: 8, Pages: 956-963 Pages count : 8 DOI: 10.1134/S003602361308007X | ||||||
Tags | Ruthenium; Nitrosyl; Trans Coordinate; Nitrosyl Chloride; Ruthenium Chloride | ||||||
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Affiliations |
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Abstract:
Aqueous solutions of ruthenium nitrosyl chloride complexes have been studied by14N, 15N, 17O, 99Ru, and 35Cl NMR. Individual complex species have been identified and the corresponding chemical shifts have been determined. The primary aquation product of the pentachloronitrosylruthenate ion is the cis-[RuNO(H2O)Cl4]− complex, which subsequently undergoes isomerization. The equilibrium constants of interconversions of ruthenium nitrosyl chloride complexes in an aqueous solution at room temperature have been estimated.
Cite:
Emelʹyanov V.A.
, Fedotov M.A.
, Belyaev A.V.
, Tkachev S.V.
A Multinuclear Magnetic Resonance Study of Transformations of Ruthenium(II) Nitrosyl Chloride Complexes in Aqueous Solutions
Russian Journal of Inorganic Chemistry. 2013. V.58. N8. P.956-963. DOI: 10.1134/S003602361308007X WOS Scopus РИНЦ
A Multinuclear Magnetic Resonance Study of Transformations of Ruthenium(II) Nitrosyl Chloride Complexes in Aqueous Solutions
Russian Journal of Inorganic Chemistry. 2013. V.58. N8. P.956-963. DOI: 10.1134/S003602361308007X WOS Scopus РИНЦ
Original:
Емельянов В.А.
, Федотов М.А.
, Беляев А.В.
, Ткачёв С.В.
Исследование превращений нитрозохлоридных комплексов рутения (II) в водных растворах методом многоядерного ЯМР
Журнал неорганической химии. 2013. Т.58. №8. С.1073-1081. DOI: 10.7868/S0044457X13080072 РИНЦ
Исследование превращений нитрозохлоридных комплексов рутения (II) в водных растворах методом многоядерного ЯМР
Журнал неорганической химии. 2013. Т.58. №8. С.1073-1081. DOI: 10.7868/S0044457X13080072 РИНЦ
Dates:
Submitted: | Oct 30, 2012 |
Published print: | Aug 1, 2013 |
Published online: | Aug 8, 2013 |
Identifiers:
Web of science | WOS:000323060300014 |
Scopus | 2-s2.0-84882237216 |
Elibrary | 20457737 |
Chemical Abstracts | 2013:1229563 |
Chemical Abstracts (print) | 159:690537 |
OpenAlex | W2040269327 |