Electronic Switch in the Carbon-Centered [Re 12CS 17(CN) 6] n- Nanocluster Full article
Journal |
Nanoscale Research Letters
ISSN: 1931-7573 , E-ISSN: 1556-276X |
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Output data | Year: 2009, Volume: 4, Number: 9, Pages: 1110-1114 Pages count : 5 DOI: 10.1007/s11671-009-9354-2 | ||||||
Tags | 12-Rhenium nanocluster, 13C NMR, DFT, Electron localization function, Switch | ||||||
Authors |
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Affiliations |
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Funding (3)
1 | Russian Foundation for Basic Research | 08-03-00826 |
2 | Russian Foundation for Basic Research | 07-03-00912 |
3 | Президиум РАН |
Abstract:
An abrupt change in internuclear Re-Re distances between {Re 6} subunits in the carbon-centered [Re 12μ 6-CS 17(CN) 6] n- complexes caused by the change of the oxidation state (n = 6, 8) is first theoretically shown to be possibly controlled by an external electric field. 13C NMR signal is shown to change over ~400 ppm (~37G) for μ 6-C atom together with n. Thereby, the metal cluster [Re 12μ 6-CS 17(CN) 6] n- can be considered as a perspective model of a molecular switch.
Cite:
Gabuda S.P.
, Kozlova S.G.
, Mironov Y.V.
, Fedorov V.E.
Electronic Switch in the Carbon-Centered [Re 12CS 17(CN) 6] n- Nanocluster
Nanoscale Research Letters. 2009. V.4. N9. P.1110-1114. DOI: 10.1007/s11671-009-9354-2 WOS Scopus РИНЦ
Electronic Switch in the Carbon-Centered [Re 12CS 17(CN) 6] n- Nanocluster
Nanoscale Research Letters. 2009. V.4. N9. P.1110-1114. DOI: 10.1007/s11671-009-9354-2 WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Apr 21, 2009 |
Accepted: | May 14, 2009 |
Published online: | May 30, 2009 |
Published print: | Sep 1, 2009 |
Identifiers:
Web of science | WOS:000269013100022 |
Scopus | 2-s2.0-70349987792 |
Elibrary | 15301310 |
Chemical Abstracts | 2009:1045713 |
Chemical Abstracts (print) | 154:78300 |
OpenAlex | W2126024174 |