Substituted Derivatives of tris(Butadiene)-Molybdenum and tris(Butadiene)-Tungsten - the Molecular-Structures of (CH2=CMeCMe=CH2)3Mo, (CH2=CMeCMe=CH2)3W Full article
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Journal of Organometallic Chemistry
ISSN: 0022-328X |
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Output data | Year: 1986, Volume: 299, Number: 3, Pages: 347-355 Pages count : 9 DOI: 10.1016/0022-328X(86)84009-8 | ||
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Abstract:
Tris(substituted butadiene) complexes of molybdenum and tungsten have been prepared by the reduction of the metal halides with anthracene-activated magnesium in the presence of the appropriate diene. An X-ray diffraction study has shown tris(2,3-dimethylbutadiene)molybdenum and its tungsten analogue to be isomorphous, with each diene unit displaying a long—short—long bond alternation, and having short metal to terminal carbon atom distances, in marked contrast to the unsubstituted complexes.
Cite:
Bogdanovic B.
, Bönnemann H.
, Goddard R.
, Startsev A.
, Wallis J.M.
Substituted Derivatives of tris(Butadiene)-Molybdenum and tris(Butadiene)-Tungsten - the Molecular-Structures of (CH2=CMeCMe=CH2)3Mo, (CH2=CMeCMe=CH2)3W
Journal of Organometallic Chemistry. 1986. V.299. N3. P.347-355. DOI: 10.1016/0022-328X(86)84009-8 WOS Scopus РИНЦ
Substituted Derivatives of tris(Butadiene)-Molybdenum and tris(Butadiene)-Tungsten - the Molecular-Structures of (CH2=CMeCMe=CH2)3Mo, (CH2=CMeCMe=CH2)3W
Journal of Organometallic Chemistry. 1986. V.299. N3. P.347-355. DOI: 10.1016/0022-328X(86)84009-8 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 8, 1985 |
Published print: | Jan 28, 1986 |
Published online: | Apr 16, 2001 |
Identifiers:
Web of science | WOS:A1986AZA5200009 |
Scopus | 2-s2.0-0000911849 |
Elibrary | 29359707 |
Chemical Abstracts | 1986:626881 |
Chemical Abstracts (print) | 105:226881 |
OpenAlex | W1975465896 |