Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol Full article
Journal |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045 |
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Output data | Year: 2017, Volume: 56, Number: 45, Pages: 13240-13253 Pages count : 14 DOI: 10.1021/acs.iecr.7b01636 | ||||||||||
Tags | OXYGENATED HYDROCARBONS; CATALYSTS; ALKANES | ||||||||||
Authors |
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Affiliations |
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Funding (2)
1 | European Commission | 310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT |
2 | The Ministry of Education and Science of the Russian Federation | 14.Z50.31.0013 |
Abstract:
The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modelling a complex reaction network was taken into account considering formation not only hydrogen and CO2, but also a range of alkanes in various side reactions. Parameter investigation revealed an
adequate description of the experimental data. Influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated combusting alkanes formed during APR reaction.
Cite:
Murzin D.Y.
, Garcia S.
, Russo V.
, Kilpiö T.
, Godina L.I.
, Tokarev A.V.
, Kirilin A.V.
, Simakova I.L.
, Poulston S.
, Sladkovskii D.A.
, Warna J.
Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol
Industrial and Engineering Chemistry Research. 2017. V.56. N45. P.13240-13253. DOI: 10.1021/acs.iecr.7b01636 WOS Scopus РИНЦ
Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol
Industrial and Engineering Chemistry Research. 2017. V.56. N45. P.13240-13253. DOI: 10.1021/acs.iecr.7b01636 WOS Scopus РИНЦ
Dates:
Submitted: | Apr 18, 2017 |
Accepted: | Jun 30, 2017 |
Published online: | Jul 14, 2017 |
Published print: | Nov 15, 2017 |
Identifiers:
Web of science | WOS:000415785500037 |
Scopus | 2-s2.0-85034043817 |
Elibrary | 31053390 |
Chemical Abstracts | 2017:1100388 |
Chemical Abstracts (print) | 167:531729 |
OpenAlex | W2728062393 |