A New Ti9O10 Nanophase Prepared by Heat-Treating Nonstoichiometric Milled TiOy Nanopowder Full article
Journal |
Inorganic Materials
ISSN: 0020-1685 , E-ISSN: 1608-3172 |
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Output data | Year: 2018, Volume: 54, Number: 6, Pages: 568-574 Pages count : 7 DOI: 10.1134/S0020168518060158 | ||||||
Tags | TiOy titanium monoxide high-energy milling nanocrystal structural transformations electronic structure | ||||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Science Foundation | 14-23-00025 |
Abstract:
A Ti9O10 nanophase (sp. gr. Immm) has been synthesized via high-energy milling followed by prolonged high-temperature vacuum heat treatment of nonstoichiometric TiOy titanium monoxide. The atomic structure and microstructure of Ti9O10 have been investigated by X-ray powder diffraction and high-resolution transmission electron microscopy. According to quantum-chemical calculation results, macrocrystalline Ti9O10 is less energetically favorable than a disordered cubic phase of the same composition, TiO10/9, so the formation of the former phase is due to size effects.
Cite:
Valeeva A.A.
, Kostenko M.G.
, Nazarova S.Z.
, Gerasimov E.Y.
, Rempel A.A.
A New Ti9O10 Nanophase Prepared by Heat-Treating Nonstoichiometric Milled TiOy Nanopowder
Inorganic Materials. 2018. V.54. N6. P.568-574. DOI: 10.1134/S0020168518060158 WOS Scopus РИНЦ
A New Ti9O10 Nanophase Prepared by Heat-Treating Nonstoichiometric Milled TiOy Nanopowder
Inorganic Materials. 2018. V.54. N6. P.568-574. DOI: 10.1134/S0020168518060158 WOS Scopus РИНЦ
Original:
Валеева А.А.
, Костенко М.Г.
, Назарова С.З.
, Герасимов Е.Ю.
, Ремпель А.А.
Новая нанофаза Ti9O10, полученная термообработкой нестехиометрического размолотого нанопорошка TiOy
Неорганические материалы. 2018. Т.54. №6. С.597-604. DOI: 10.7868/S0002337X18060088 РИНЦ
Новая нанофаза Ti9O10, полученная термообработкой нестехиометрического размолотого нанопорошка TiOy
Неорганические материалы. 2018. Т.54. №6. С.597-604. DOI: 10.7868/S0002337X18060088 РИНЦ
Dates:
Submitted: | Nov 24, 2017 |
Published print: | Jun 1, 2018 |
Published online: | Jun 6, 2018 |
Identifiers:
Web of science | WOS:000434473700008 |
Scopus | 2-s2.0-85048191775 |
Elibrary | 35749428 |
Chemical Abstracts | 2018:1096738 |
OpenAlex | W2807361408 |