On the Mechanisms of Selective Bioinspired Oxidations Catalyzed by Aminopyridine Manganese Complexes Conference Abstracts
Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015 , Казань |
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Source | EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts Compilation, Boreskov Institute of Catalysis. Novosibirsk.2015. 2184 c. ISBN 9785906376107. РИНЦ |
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Output data | Year: 2015, Article number : ISO-OP13, Pages count : 2 | ||||
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 14-03-00102 |
Abstract:
Insights into the mechanisms of (1) selective epoxidations and (2) C-H oxidations mediated by aminopyridine manganese complexes have been achieved on the basis of kinetic (Hammett plot analysis, KIE measuments) and isotopic (18O) labelling studies. For the first time, the incorporation of labelled oxygen into the products of oxidation catalyzed by aminopyridine manganese complexes in the presence of H2 18O was observed. The data obtained bear evidence in favour of the key role of MnV-oxo species, the most likely catalytically active sites of both processes.
Cite:
Talsi E.P.
, Ottenbacher R.V.
, Bryliakov K.P.
On the Mechanisms of Selective Bioinspired Oxidations Catalyzed by Aminopyridine Manganese Complexes
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – Boreskov Institute of Catalysis., 2015. – C.2078-2079. – ISBN 9785906376107.
On the Mechanisms of Selective Bioinspired Oxidations Catalyzed by Aminopyridine Manganese Complexes
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – Boreskov Institute of Catalysis., 2015. – C.2078-2079. – ISBN 9785906376107.
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