Catalytic Condensation of Glycolaldehyde and Glyceraldehyde with Formaldehyde in Neutral and Weakly Alkaline Aqueous Media: Kinetics and Mechanism Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2009, Volume: 50, Number: 2, Pages: 297-303 Pages count : 7 DOI: 10.1134/S0023158409020219 | ||||
Tags | Monosaccharide; Apparent Activation Energy; Glyceraldehyde; Apparent Rate Constant; Aldol Condensation | ||||
Authors |
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Affiliations |
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Funding (3)
1 | The Ministry of Education and Science of the Russian Federation | 2.1.1.1969 |
2 | Президиум РАН | |
3 | Council for Grants of the President of the Russian Federation | НШ-6526.2006.3 |
Abstract:
The kinetics of glycolaldehyde and glyceraldehyde condensation with formaldehyde in a neutral aqueous medium in the presence of homogeneous phosphates and in a weakly alkaline medium in the presence of MgO was studied. The temperature dependences of the observed kinetic constants and the apparent activation energies of the reactions were determined. A reaction scheme for the interaction of lower monosaccharides with formaldehyde was derived from analyses of the reaction products.
Cite:
Delidovich I.V.
, Simonov A.N.
, Pestunova O.P.
, Parmon V.N.
Catalytic Condensation of Glycolaldehyde and Glyceraldehyde with Formaldehyde in Neutral and Weakly Alkaline Aqueous Media: Kinetics and Mechanism
Kinetics and Catalysis. 2009. V.50. N2. P.297-303. DOI: 10.1134/S0023158409020219 WOS Scopus РИНЦ
Catalytic Condensation of Glycolaldehyde and Glyceraldehyde with Formaldehyde in Neutral and Weakly Alkaline Aqueous Media: Kinetics and Mechanism
Kinetics and Catalysis. 2009. V.50. N2. P.297-303. DOI: 10.1134/S0023158409020219 WOS Scopus РИНЦ
Original:
Делидович И.В.
, Симонов А.Н.
, Пестунова О.П.
, Пармон В.Н.
Кинетика и механизм каталитической конденсации гликолевого и глицеринового альдегидов с формальдегидом в нейтральной и слабощелочной водных средах
Кинетика и катализ. 2009. Т.50. №2. С.314-321. РИНЦ
Кинетика и механизм каталитической конденсации гликолевого и глицеринового альдегидов с формальдегидом в нейтральной и слабощелочной водных средах
Кинетика и катализ. 2009. Т.50. №2. С.314-321. РИНЦ
Dates:
Submitted: | Mar 28, 2008 |
Published print: | Mar 1, 2009 |
Published online: | Apr 24, 2009 |
Identifiers:
Web of science | WOS:000265499100021 |
Scopus | 2-s2.0-65349151867 |
Elibrary | 14718803 |
Chemical Abstracts | 2009:496080 |
Chemical Abstracts (print) | 151:100701 |
OpenAlex | W2090329842 |