103Rh and 17O NMR Study of Oligomer Rhodium(III) Sulfates in Aqueous Solutions Full article
Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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Output data | Year: 2009, Volume: 35, Number: 11, Pages: 824-829 Pages count : 6 DOI: 10.1134/S1070328409110062 | ||||
Tags | Rhodium; Ionic Pair; Coordination Chemistry; Sulfate Complex; Partial Content | ||||
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Abstract:
By virtue of 103Rh-, 17O-NMR, electrophoresis in agarose gel, and pH-metry, we report on the formation of rhodium(III) sulfate complexes in aqueous solutions. At higher concentrations of sulfuric acid (above 3 M), more than 90% of metal was found to stay in the state of symmetric polynuclear complexes containing magnetically equivalent rhodium atoms. We also labeled the 103Rh-NMR chemical shifts for the complexes with 3, 4 and 6 metal atoms in the spectra.
Cite:
Belyaev A.V.
, Fedotov M.A.
, Vorobʹyova S.N.
103Rh and 17O NMR Study of Oligomer Rhodium(III) Sulfates in Aqueous Solutions
Russian Journal of Coordination Chemistry. 2009. V.35. N11. P.824-829. DOI: 10.1134/S1070328409110062 WOS Scopus РИНЦ
103Rh and 17O NMR Study of Oligomer Rhodium(III) Sulfates in Aqueous Solutions
Russian Journal of Coordination Chemistry. 2009. V.35. N11. P.824-829. DOI: 10.1134/S1070328409110062 WOS Scopus РИНЦ
Original:
Беляев А.В.
, Федотов М.А.
, Воробьёва С.Н.
Олигомерные сульфаты RH(III) в водных растворах по данным ЯМР 103RH и 17O
Координационная химия. 2009. Т.35. №11. С.834-839. РИНЦ
Олигомерные сульфаты RH(III) в водных растворах по данным ЯМР 103RH и 17O
Координационная химия. 2009. Т.35. №11. С.834-839. РИНЦ
Dates:
Submitted: | Feb 26, 2009 |
Published print: | Nov 1, 2009 |
Published online: | Nov 15, 2009 |
Identifiers:
Web of science | WOS:000271810100006 |
Scopus | 2-s2.0-70450119734 |
Elibrary | 15300413 |
Chemical Abstracts | 2009:1421302 |
Chemical Abstracts (print) | 154:100043 |
OpenAlex | W1964143991 |