Decarboxylation of Fatty Acids over Pd Supported on Mesoporous Carbon Full article
Conference |
3rd International Symposium on Carbon for Catalysis 09-12 Nov 2008 , Berlin |
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Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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Output data | Year: 2010, Volume: 150, Number: 1-2, Pages: 28-31 Pages count : 4 DOI: 10.1016/j.cattod.2009.07.064 | ||||
Tags | Decarboxylation, Fatty acids, Mesoporous carbon, Palladium | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Suomen Akatemia |
Abstract:
Fatty acid decarboxylation was studied in a semibatch reactor over 1 wt.% Pd/C (Sibunit) using five different fatty acids, C17–C20 and C22, as feeds. The same decarboxylation rates were obtained for pure fatty acids, whereas extensive catalyst poisoning and/or sintering and coking occurred with low purity fatty acids as reactants. One reason for catalyst poisoning using behenic acid (C22) as a feedstock was its high phosphorus content. The decarboxylation rate of fatty acids decreased also with increasing fatty acid to metal ratio.
Cite:
Simakova I.
, Simakova O.
, Maki-Arvela P.
, Murzin D.Y.
Decarboxylation of Fatty Acids over Pd Supported on Mesoporous Carbon
Catalysis Today. 2010. V.150. N1-2. P.28-31. DOI: 10.1016/j.cattod.2009.07.064 WOS Scopus РИНЦ
Decarboxylation of Fatty Acids over Pd Supported on Mesoporous Carbon
Catalysis Today. 2010. V.150. N1-2. P.28-31. DOI: 10.1016/j.cattod.2009.07.064 WOS Scopus РИНЦ
Dates:
Published online: | Aug 7, 2009 |
Published print: | Feb 26, 2010 |
Identifiers:
Web of science | WOS:000275566700006 |
Scopus | 2-s2.0-76349103044 |
Elibrary | 15323971 |
Chemical Abstracts | 2010:198000 |
Chemical Abstracts (print) | 152:432774 |
OpenAlex | W2032590040 |