Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review Review
Journal |
Journal of Cluster Science
ISSN: 1040-7278 , E-ISSN: 1572-8862 |
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Output data | Year: 2019, Volume: 30, Number: 5, Pages: 1283-1316 Pages count : 34 DOI: 10.1007/s10876-019-01567-y | ||||||||
Tags | Cage compounds; Catalytic activity; Coordination polymers; High-nuclearity; Metallagermsesquioxanes; Metallasilsesquioxanes; Single-crystal X-ray diffraction; Supramolecular design | ||||||||
Authors |
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Affiliations |
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Funding (4)
1 | The Ministry of Education and Science of the Russian Federation | |
2 | Russian Foundation for Basic Research | 17-03-00993 |
3 | Ministry of Science and Higher Education of the Russian Federation | 0239-2019-0003 |
4 | Russian Foundation for Basic Research | 19-03-00488 (АААА-А19-119011690147-2) |
Abstract:
In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.
Cite:
Levitsky M.M.
, Zubavichus Y.V.
, Korlyukov A.A.
, Khrustalev V.N.
, Shubina E.S.
, Bilyachenko A.N.
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
Journal of Cluster Science. 2019. V.30. N5. P.1283-1316. DOI: 10.1007/s10876-019-01567-y WOS Scopus РИНЦ РИНЦ
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
Journal of Cluster Science. 2019. V.30. N5. P.1283-1316. DOI: 10.1007/s10876-019-01567-y WOS Scopus РИНЦ РИНЦ
Dates:
Submitted: | Mar 15, 2019 |
Published online: | May 4, 2019 |
Published print: | Sep 1, 2019 |
Identifiers:
Web of science | WOS:000487900100015 |
Scopus | 2-s2.0-85065395332 |
Elibrary | 38690719 , 41792994 |
Chemical Abstracts | 2019:887763 |
OpenAlex | W2944365947 |