Hexaazide Octahedral Molybdenum Cluster Complexes: Synthesis, Properties and the Evidence of Hydrolysis Full article
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Journal of Molecular Structure
ISSN: 0022-2860 |
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Output data | Year: 2017, Volume: 1134, Pages: 237-243 Pages count : 7 DOI: 10.1016/j.molstruc.2016.12.052 | ||||||||||||
Tags | Crystal structure; ESI mass spectrometry; Hydrolysis; Luminescence; Octahedral molybdenum clusters | ||||||||||||
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Abstract:
This article reports the synthesis, crystal structure of new molybdenum hexaazide cluster complex (nBu4N)2[{Mo6I8}(N3)6] (3) and comparison of its photophysical and electrochemical properties to those of earlier reported analogues (nBu4N)2[{Mo6X8}(N3)6] (X = Cl, Br). Additionally, the dimerisation of 3 as a result of hydrolysis was revealed by mass spectrometry and single crystal X-Ray diffraction. Indeed, the structurally characterised compound (nBu4N)4[({Mo6I8}(N3)5)2O] represents the first example of oxo-bridged dimer of octahedral molybdenum clusters complexes.
Cite:
Vorotnikov Y.A.
, Efremova O.A.
, Novozhilov I.N.
, Yanshole V.V.
, Kuratieva N.V.
, Brylev K.A.
, Kitamura N.
, Mironov Y.V.
, Shestopalov M.A.
Hexaazide Octahedral Molybdenum Cluster Complexes: Synthesis, Properties and the Evidence of Hydrolysis
Journal of Molecular Structure. 2017. V.1134. P.237-243. DOI: 10.1016/j.molstruc.2016.12.052 WOS Scopus РИНЦ
Hexaazide Octahedral Molybdenum Cluster Complexes: Synthesis, Properties and the Evidence of Hydrolysis
Journal of Molecular Structure. 2017. V.1134. P.237-243. DOI: 10.1016/j.molstruc.2016.12.052 WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Oct 29, 2016 |
Accepted: | Dec 20, 2016 |
Published online: | Dec 27, 2016 |
Published print: | Apr 15, 2017 |
Identifiers:
Web of science | WOS:000394919100028 |
Scopus | 2-s2.0-85008145408 |
Elibrary | 29467602 |
Chemical Abstracts | 2017:27632 |
Chemical Abstracts (print) | 166:174405 |
OpenAlex | W2564835262 |