PO23– and AsO3–: Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8–, [{Re4As2(AsO)2}(CN)12]8–, and [{Re4(AsO)4}(CN)12]8– Full article
Journal |
Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X |
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Output data | Year: 2019, Volume: 58, Number: 11, Pages: 7368-7373 Pages count : 6 DOI: 10.1021/acs.inorgchem.9b00520 | ||||
Tags | RHENIUM CLUSTER; CRYSTAL-STRUCTURE; Se; COMPLEXES; Te; MOLYBDENUM; FACILE | ||||
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Abstract:
New tetrahedral anionic rhenium cluster complexes [{Re4(PO)3(PO2)}(CN)12]8– (1) and [{Re4As2(AsO)2}(CN)12]8– (2) have been synthesized by the reaction of ReI3 with NaCN and Pred or KCN and Asgray, respectively. Compound 2 was further oxidized by aqueous H2O2 to produce the cluster anion [{Re4(AsO)4}(CN)12]8– (3). The anions contain new pnictogen/oxygen-based ligands, PO23– and AsO3–, which were stabilized by the coordination to the triangular faces of the tetrahedral Re4 metallocluster in μ3-mode. All three compounds were crystallized as either sodium or potassium salts, and their crystal structures were determined by single crystal X-ray diffraction analysis.
Cite:
Pronin A.S.
, Smolentsev A.I.
, Kozlova S.G.
, Novozhilov I.N.
, Mironov Y.V.
PO23– and AsO3–: Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8–, [{Re4As2(AsO)2}(CN)12]8–, and [{Re4(AsO)4}(CN)12]8–
Inorganic Chemistry. 2019. V.58. N11. P.7368-7373. DOI: 10.1021/acs.inorgchem.9b00520 WOS Scopus РИНЦ
PO23– and AsO3–: Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8–, [{Re4As2(AsO)2}(CN)12]8–, and [{Re4(AsO)4}(CN)12]8–
Inorganic Chemistry. 2019. V.58. N11. P.7368-7373. DOI: 10.1021/acs.inorgchem.9b00520 WOS Scopus РИНЦ
Dates:
Submitted: | Feb 21, 2019 |
Published online: | May 16, 2019 |
Published print: | Jun 3, 2019 |
Identifiers:
Web of science | WOS:000470332200027 |
Scopus | 2-s2.0-85066122357 |
Elibrary | 41621517 |
Chemical Abstracts | 2019:948814 |
Chemical Abstracts (print) | 170:614553 |
OpenAlex | W2945566471 |