23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]− Full article
Journal |
Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X |
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Output data | Year: 2018, Volume: 57, Number: 2, Pages: 811-820 Pages count : 10 DOI: 10.1021/acs.inorgchem.7b02760 | ||||||||||||||
Tags | CRYSTAL-STRUCTURE; HEXANUCLEAR MOLYBDENUM; ELECTRONIC-STRUCTURE; VIBRATIONAL-SPECTRA; SOLUTION CHEMISTRY; CHLORIDE CLUSTER; BASIS-SETS; BR; REDOX; Cl | ||||||||||||||
Authors |
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Abstract:
Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e– cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.
Cite:
Vorotnikova N.A.
, Vorotnikov Y.A.
, Novozhilov I.N.
, Syrokvashin M.M.
, Nadolinny V.A.
, Kuratieva N.V.
, Benoit D.M.
, Mironov Y.V.
, Walton R.I.
, Clarkson G.J.
, Kitamura N.
, Sutherland A.J.
, Shestopalov M.A.
, Efremova O.A.
23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]−
Inorganic Chemistry. 2018. V.57. N2. P.811-820. DOI: 10.1021/acs.inorgchem.7b02760 WOS Scopus РИНЦ
23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]−
Inorganic Chemistry. 2018. V.57. N2. P.811-820. DOI: 10.1021/acs.inorgchem.7b02760 WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Oct 27, 2017 |
Accepted: | Dec 22, 2017 |
Published online: | Dec 22, 2017 |
Published print: | Jan 15, 2018 |
Identifiers:
Web of science | WOS:000422810900034 |
Scopus | 2-s2.0-85040562203 |
Elibrary | 35489265 |
Chemical Abstracts | 2017:2014596 |
Chemical Abstracts (print) | 168:103796 |
OpenAlex | W2773683131 |