Catalytic Properties of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8– in Selective Oxidations with Hydrogen Peroxide Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2010, Volume: 51, Number: 6, Pages: 816-822 Pages count : 7 DOI: 10.1134/S0023158410060066 | ||||
Tags | MOLECULAR-MODELS; EPOXIDATION; COMPLEXES; SIEVES; ACIDS | ||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 09-03-91333 |
2 | German Research Foundation | KO 2288/9-1 |
Abstract:
The catalytic properties of the sandwich polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8−, which contains two (B-α-AsIIIW9O33) fragments linked together by a “belt” consisting of one octahedral WO(H2O)4+ and two square-pyramidal Ti(OH)3+ groups, have been investigated in the selective liquid-phase oxidation of organic compounds by aqueous hydrogen peroxide. The polyoxometalate shows high catalytic activity and selectivity in the oxidation of alkenes, alcohols, diols, and thioethers. The composition of the reaction products indicates that hydrogen peroxide is activated via a heterolytic mechanism.
Cite:
Donoeva B.G.
, Trubitsyna T.A.
, Al-Kadamany G.
, Kortz U.
, Kholdeeva O.A.
Catalytic Properties of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8– in Selective Oxidations with Hydrogen Peroxide
Kinetics and Catalysis. 2010. V.51. N6. P.816-822. DOI: 10.1134/S0023158410060066 WOS Scopus РИНЦ
Catalytic Properties of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8– in Selective Oxidations with Hydrogen Peroxide
Kinetics and Catalysis. 2010. V.51. N6. P.816-822. DOI: 10.1134/S0023158410060066 WOS Scopus РИНЦ
Original:
Доноева Б.Г.
, Трубицына Т.А.
, Аль-Кадамани Г.
, Корц У.
, Холдеева О.А.
Каталитические свойства полиоксометаллата [Ti2(OH)2As2W19O67(H2O)]8 в реакциях селективного окисления пероксидом водорода
Кинетика и катализ. 2010. Т.51. №6. С.843-849. РИНЦ
Каталитические свойства полиоксометаллата [Ti2(OH)2As2W19O67(H2O)]8 в реакциях селективного окисления пероксидом водорода
Кинетика и катализ. 2010. Т.51. №6. С.843-849. РИНЦ
Dates:
Submitted: | Dec 30, 2009 |
Published print: | Dec 1, 2010 |
Published online: | Dec 16, 2010 |
Identifiers:
Web of science | WOS:000285363900006 |
Scopus | 2-s2.0-79951884758 |
Elibrary | 16680178 |
Chemical Abstracts | 2010:1565807 |
Chemical Abstracts (print) | 154:286590 |
OpenAlex | W2092644062 |