On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2010, Volume: 51, Number: 6, Pages: 828-831 Pages count : 4 DOI: 10.1134/S002315841006008X | ||||
Tags | THERMODYNAMIC ANALYSIS; NANOPARTICLE SIZE; ACID | ||||
Authors |
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Affiliations |
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Funding (2)
1 | The Ministry of Education and Science of the Russian Federation | 02.740.11.5178 |
2 | Suomen Akatemia |
Abstract:
Quantitative description for turnover frequency dependence on the metal cluster size for a two-step catalytic cycle was performed based on a thermodynamic approach, which accounts for changes of the chemical potential upon adsorption depending on the metal cluster size. Such analysis revealed a possibility for turnover frequency to exhibit a maximum. A very good correspondence between calculated and experimental data in hydrogenation and decarboxylation reactions over palladium was achieved.
Cite:
Murzin D.Y.
, Simakova I.L.
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Kinetics and Catalysis. 2010. V.51. N6. P.828-831. DOI: 10.1134/S002315841006008X WOS Scopus РИНЦ
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Kinetics and Catalysis. 2010. V.51. N6. P.828-831. DOI: 10.1134/S002315841006008X WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Murzin D.Y.
, Simakova I.L.
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Кинетика и катализ. 2010. V.51. N6. P.855-858. RSCI РИНЦ
On Quantitative Description of Metal Particles Size Effect in Catalytic Kinetics
Кинетика и катализ. 2010. V.51. N6. P.855-858. RSCI РИНЦ
Dates:
Submitted: | Nov 13, 2009 |
Published print: | Dec 1, 2010 |
Published online: | Dec 16, 2010 |
Identifiers:
Web of science | WOS:000285363900008 |
Scopus | 2-s2.0-78650789894 |
Elibrary | 16679068 |
Chemical Abstracts | 2010:1565834 |
Chemical Abstracts (print) | 154:96301 |
OpenAlex | W1991480638 |