γ-Hydroxypropylation of 2,6-Dialkyl(aryl)phenols with Allyl Alcohol and Its Derivatives
Science article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of General Chemistry
ISSN: 1070-3632
, E-ISSN: 1608-3350
|
| Output data |
Year: 2010,
Volume: 80,
Number: 11,
Pages: 2290-2297
Pages count
: 8
DOI:
10.1134/S1070363210110101
|
| Authors |
Krysin A.P.
1
,
Khalikova N.U.
1
,
Khlebnikova T.B.
2
,
Nogina N.I.
1
,
Mamatyuk V.I.
1
|
| Affiliations |
| 1 |
Vorozhtzov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Science
|
| 2 |
Boreskov Institute of Catalysis SB RAS
|
|
The composition of the products of the reaction of 2,6-disubstituted phenols with allyl alcohol and its derivatives in an alkaline medium was investigated, the conditions for carrying out the reaction with the predominant formation of 4-(3-hydroxypropyl)-2,6-dialkyl(aryl)phenols were found, and its mechanism was suggested. The reaction was examined on an industrial scale. An important result is the practical demonstration of alkaline catalysis performed under homogeneous conditions with participation of phenols, when the used alkaline catalyst is recovered in the process without the formation of waste waters.