Platinum Acetate Blue: Synthesis and Characterization Full article
Journal |
Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X |
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Output data | Year: 2014, Volume: 53, Number: 16, Pages: 8397-8406 Pages count : 10 DOI: 10.1021/ic500940a | ||||||
Tags | ALPHA-PYRIDONE BLUE; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURES; COMPLEXES; 1-METHYLURACIL; COORDINATION; SPECTRUM; VALENCE | ||||||
Authors |
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Affiliations |
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Funding (4)
1 | Russian Foundation for Basic Research | 12-03-00917 |
2 | Russian Foundation for Basic Research | 12-03-31325 |
3 | Council for Grants of the President of the Russian Federation | НШ-1712.2014.3 |
4 | Президиум РАН |
Abstract:
Platinum acetate blue (PAB) of the empirical formula Pt(OOCMe)2.5±0.25, a byproduct in the synthesis of crystalline platinum(II) acetate Pt4(OOCMe)8, is an X-ray amorphous substance containing platinum in the oxidation state between (II) and (III). Typical PAB samples were studied with X-ray diffraction, differential thermal analysis-thermogravimetric, extended X-ray absorption fine structure, scanning electron microscopy, transmission electron microscopy, magnetochemistry, and combined quantum chemical density functional theory-molecular mechanics modeling to reveal the main structural features of the PAB molecular building blocks. The applicability of PAB to the synthesis of platinum complexes was demonstrated by the preparation of the new homo- and heteronuclear complexes Pt(II)(dipy)(OOCMe)2 (1), Pt(II)(μ-OOCMe)4Co(II)(OH2) (2), and Pt(III)2(OOCMe)4(O3SPhMe)2 (3) with the use of PAB as starting material.
Cite:
Cherkashina N.V.
, Kochubey D.I.
, Kanazhevskiy V.V.
, Zaikovskii V.I.
, Ivanov V.K.
, Markov A.A.
, Klyagina A.P.
, Dobrokhotova Z.V.
, Kozitsyna N.Y.
, Baranovsky I.B.
, Ellert O.G.
, Efimov N.N.
, Nefedov S.E.
, Novotortsev V.M.
, Vargaftik M.N.
, Moiseev I.I.
Platinum Acetate Blue: Synthesis and Characterization
Inorganic Chemistry. 2014. V.53. N16. P.8397-8406. DOI: 10.1021/ic500940a WOS Scopus РИНЦ
Platinum Acetate Blue: Synthesis and Characterization
Inorganic Chemistry. 2014. V.53. N16. P.8397-8406. DOI: 10.1021/ic500940a WOS Scopus РИНЦ
Dates:
Submitted: | Apr 23, 2014 |
Published online: | Aug 7, 2014 |
Published print: | Aug 18, 2014 |
Identifiers:
Web of science | WOS:000340576900024 |
Scopus | 2-s2.0-84906246884 |
Elibrary | 23983296 |
Chemical Abstracts | 2014:1321295 |
Chemical Abstracts (print) | 161:327659 |
OpenAlex | W2324818415 |