Structural Paradox in Submonolayer Chlorine Coverage on Au(111) Full article
Journal |
Physical Review B, Condensed Matter and Materials Physics (up to 2016)
ISSN: 1098-0121 , E-ISSN: 1550-235X |
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Output data | Year: 2014, Volume: 89, Number: 19, Pages: 195425-1 -19542-5 Pages count : 5 DOI: 10.1103/PhysRevB.89.195425 | ||||||||
Tags | INITIO MOLECULAR-DYNAMICS; TOTAL-ENERGY CALCULATIONS; ADATOMS; CONSEQUENCES; METAL; PAIR; IR | ||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 12-02-01188 (01201261320) |
2 | Russian Foundation for Basic Research | 12-02-31869 |
Abstract:
In this work, we present a combined low-temperature scanning tunneling microscopy (STM) and density functional theory (DFT) study of chlorine adsorption on Au(111) at low coverages. Our STM study of Cl/Au(111) system has shown that at submonolayer coverages (θ< 0.1 ML) chlorine atoms form chainlike structures with abnormally short distances of 3.8 Å between them. Our DFT calculations have shown that chlorine atoms can interact with each other through distortion of the substrate and this indirect elastic interaction is strong enough to affect their arrangement in the chainlike structures.
Cite:
Zheltov V.V.
, Cherkez V.V.
, Andryushechkin B.V.
, Zhidomirov G.M.
, Kierren B.
, Fagot-Revurat Y.
, Malterre D.
, Eltsov K.N.
Structural Paradox in Submonolayer Chlorine Coverage on Au(111)
Physical Review B, Condensed Matter and Materials Physics (up to 2016). 2014. V.89. N19. P.195425-1 -19542-5. DOI: 10.1103/PhysRevB.89.195425 WOS Scopus РИНЦ
Structural Paradox in Submonolayer Chlorine Coverage on Au(111)
Physical Review B, Condensed Matter and Materials Physics (up to 2016). 2014. V.89. N19. P.195425-1 -19542-5. DOI: 10.1103/PhysRevB.89.195425 WOS Scopus РИНЦ
Dates:
Submitted: | Feb 14, 2014 |
Accepted: | Apr 21, 2014 |
Published print: | May 1, 2014 |
Published online: | May 19, 2014 |
Identifiers:
Web of science | WOS:000336759100005 |
Scopus | 2-s2.0-84901422325 |
Elibrary | 22069949 |
Chemical Abstracts | 2014:1534575 |
OpenAlex | W2322547384 |