Influence of Cluster Size Distribution on Cluster Size Dependent Catalytic Kinetics Full article
Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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Output data | Year: 2011, Volume: 141, Number: 7, Pages: 982-986 Pages count : 5 DOI: 10.1007/s10562-011-0577-3 | ||||
Tags | Cluster size, Decarboxylation, Kinetics, Particle size distribution | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Suomen Akatemia | 2000–2011 |
Abstract:
A theoretical analysis of the influence of particle size distribution on observed TOF dependence on cluster size is presented for a two step catalytic cycle. Such mechanism can display different TOF behavior including maxima. In the later case simulations demonstrated broadening of TOF curves compared to an idealized case of very narrow PSD. However, for more often observed cases with smooth TOF increase or decrease with cluster size increase incorporation of particle size distribution in kinetic analysis is not required at least for often experimentally observed particle size distributions.
Cite:
Murzin D.Y.
, Simakova I.L.
Influence of Cluster Size Distribution on Cluster Size Dependent Catalytic Kinetics
Catalysis Letters. 2011. V.141. N7. P.982-986. DOI: 10.1007/s10562-011-0577-3 WOS Scopus РИНЦ
Influence of Cluster Size Distribution on Cluster Size Dependent Catalytic Kinetics
Catalysis Letters. 2011. V.141. N7. P.982-986. DOI: 10.1007/s10562-011-0577-3 WOS Scopus РИНЦ
Dates:
Submitted: | Feb 7, 2011 |
Accepted: | Mar 3, 2011 |
Published online: | Mar 22, 2011 |
Published print: | Jul 1, 2011 |
Identifiers:
Web of science | WOS:000292652300011 |
Scopus | 2-s2.0-80051798388 |
Elibrary | 41744139 |
Chemical Abstracts | 2011:355240 |
OpenAlex | W1992527325 |