Ethylene Glycol Oxidation over Supported Catalyst in Tubular Reactor Full article
Journal |
Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212 |
||||
---|---|---|---|---|---|
Output data | Year: 2011, Volume: 172, Number: 1, Pages: 399-409 Pages count : 11 DOI: 10.1016/j.cej.2011.05.079 | ||||
Tags | Ethylene glycol oxidation, Glyoxal, Modeling and simulation, Supported catalyst | ||||
Authors |
|
||||
Affiliations |
|
Funding (3)
1 | The Ministry of Education and Science of the Russian Federation | 13.Г36.31.0001 |
2 | Russian Foundation for Basic Research | |
3 | The Ministry of Education and Science of the Russian Federation |
Abstract:
Macrokinetics for chemical transformation of ethylene glycol into glyoxal (including side-reactions) as well as 2D heterogeneous mathematical model were suggested. Numerical results obtained using this model were compared with the experimental data obtained at lab-scale and pilot reactor, and showed good correlation. It was shown that due to catalyst activity change it is possible to manage the process selectivity with respect to glyoxal in diffusion mode. The optimal value of catalyst activity providing the highest process selectivity can be found.
Cite:
Salaev M.A.
, Krejker A.A.
, Magaev O.V.
, Malʹkov V.S.
, Knyazev A.S.
, Borisova E.S.
, Khanaev V.M.
, Vodyankina O.V.
, Kurina L.N.
Ethylene Glycol Oxidation over Supported Catalyst in Tubular Reactor
Chemical Engineering Journal. 2011. V.172. N1. P.399-409. DOI: 10.1016/j.cej.2011.05.079 WOS Scopus РИНЦ
Ethylene Glycol Oxidation over Supported Catalyst in Tubular Reactor
Chemical Engineering Journal. 2011. V.172. N1. P.399-409. DOI: 10.1016/j.cej.2011.05.079 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 19, 2010 |
Accepted: | May 19, 2011 |
Published online: | May 27, 2011 |
Published print: | Aug 1, 2011 |
Identifiers:
Web of science | WOS:000295438800046 |
Scopus | 2-s2.0-79960993848 |
Elibrary | 16990179 |
Chemical Abstracts | 2011:987346 |
Chemical Abstracts (print) | 155:304121 |
OpenAlex | W1966697819 |