Tetrapalladium-Containing Polyoxotungstate [PdII4(α-P2W15O56)2]16−: A Comparative Study Full article
Journal |
Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X |
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Output data | Year: 2014, Volume: 53, Number: 21, Pages: 11778 - 11784 Pages count : 7 DOI: 10.1021/ic502080x | ||||||||
Tags | TRIVACANT HETEROPOLYTUNGSTATE DERIVATIVES; HYDROGEN-PEROXIDE; CATALYTIC-ACTIVITY; ALLYLIC ALCOHOLS; NOBLE-METALS; W-183 NMR; SANDWICH; PALLADIUM(II); COMPLEXES; KEGGIN | ||||||||
Authors |
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Affiliations |
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Funding (1)
1 | European Commission | 308051 FP7-IDEAS-ERC MOLSPINTRON |
Abstract:
The novel tetrapalladium(II)-containing polyoxometalate [PdII4(α-P2W15O56)2]16− has been prepared in aqueous medium and characterized as its hydrated sodium salt Na16[Pd4(α-P2W15O56)2]·71H2O by single-crystal XRD, elemental analysis, IR, Raman, multinuclear NMR, and UV−vis spectroscopy. The complex exists in anti and syn conformations, which form in a 2:1 ratio, and possesses unique structural characteristics in comparison with known {M4(P2W15)2} species. 31P and 183W NMR spectroscopy are consistent with the long-term stability of the both isomers in aqueous solutions.
Cite:
Izarova N.V.
, Maksimovskaya R.I.
, Willbold S.
, Kogerler P.
Tetrapalladium-Containing Polyoxotungstate [PdII4(α-P2W15O56)2]16−: A Comparative Study
Inorganic Chemistry. 2014. V.53. N21. P.11778 - 11784. DOI: 10.1021/ic502080x WOS Scopus РИНЦ
Tetrapalladium-Containing Polyoxotungstate [PdII4(α-P2W15O56)2]16−: A Comparative Study
Inorganic Chemistry. 2014. V.53. N21. P.11778 - 11784. DOI: 10.1021/ic502080x WOS Scopus РИНЦ
Dates:
Submitted: | Aug 28, 2014 |
Published online: | Oct 17, 2014 |
Published print: | Nov 3, 2014 |
Identifiers:
Web of science | WOS:000344307400048 |
Scopus | 2-s2.0-84908626185 |
Elibrary | 23998005 |
Chemical Abstracts | 2014:1767960 |
Chemical Abstracts (print) | 161:654232 |
OpenAlex | W2952451518 |