X-Ray Photoelectron Spectroscopy Study of the Charge and Spin States of Atoms in the Tetranuclear Copper(II) Complex with the Nitroxyl Radical (L) of the Composition Cu4(OH)2(OAc)4(DMF)2(L)2 Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 2014, Volume: 63, Number: 4, Pages: 826-832 Pages count : 7 DOI: 10.1007/s11172-014-0516-8 | ||||||||
Tags | Copper(II) complexes with the nitroxyl radical, DFT, X-ray photoelectron spectroscopy | ||||||||
Authors |
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Affiliations |
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Funding (5)
1 | Russian Foundation for Basic Research | 12-03-00067 |
2 | Russian Foundation for Basic Research | 12-03-00558 |
3 | Russian Foundation for Basic Research | 13-03-12401 |
4 | Siberian Branch of the Russian Academy of Sciences | |
5 | Президиум РАН |
Abstract:
The charge and spin states of atoms in the copper(II) complex with the nitroxyl radical (L) of the composition Cu4(OH)2(OAc)4(DMF)2(L)2 were studied by X-ray photoelectron spectroscopy and compared with the data of quantum chemical calculations. The spectra of copper represent a superposition of the |C−13d9〉 and |C−13d10 L〉 electronic states (C−1 = 2p5 or 3s1). All copper ions in the complex have the close-lying charge and spin states.
Cite:
Mazalov L.N.
, Kryuchkova N.A.
, Fedorenko A.D.
, Kalinkin A.V.
, Tretyakov E.V.
X-Ray Photoelectron Spectroscopy Study of the Charge and Spin States of Atoms in the Tetranuclear Copper(II) Complex with the Nitroxyl Radical (L) of the Composition Cu4(OH)2(OAc)4(DMF)2(L)2
Russian Chemical Bulletin. 2014. V.63. N4. P.826-832. DOI: 10.1007/s11172-014-0516-8 WOS Scopus РИНЦ
X-Ray Photoelectron Spectroscopy Study of the Charge and Spin States of Atoms in the Tetranuclear Copper(II) Complex with the Nitroxyl Radical (L) of the Composition Cu4(OH)2(OAc)4(DMF)2(L)2
Russian Chemical Bulletin. 2014. V.63. N4. P.826-832. DOI: 10.1007/s11172-014-0516-8 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Мазалов Л.Н.
, Крючкова Н.А.
, Федоренко А.Д.
, Калинкин А.В.
, Третьяков Е.В.
Рентгеноэлектронное изучение зарядового и спинового состояния атомов в тетраядерном комплексе меди(II) с нитроксильным радикалом (L) состава Cu4(OH)2(OАc)4(DMF)2(L)2
Известия Академии наук. Серия химическая. 2014. №4. С.826-832. РИНЦ
Рентгеноэлектронное изучение зарядового и спинового состояния атомов в тетраядерном комплексе меди(II) с нитроксильным радикалом (L) состава Cu4(OH)2(OАc)4(DMF)2(L)2
Известия Академии наук. Серия химическая. 2014. №4. С.826-832. РИНЦ
Dates:
Submitted: | Dec 26, 2013 |
Published print: | Apr 1, 2014 |
Published online: | Jan 27, 2015 |
Identifiers:
Web of science | WOS:000348593900005 |
Scopus | 2-s2.0-84921792699 |
Elibrary | 24030522 |
Chemical Abstracts | 2015:172892 |
Chemical Abstracts (print) | 162:307726 |
OpenAlex | W2030662471 |