Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation Full article
Conference |
Catalysis for sustainable development : Russian-Dutch Workshop 22-26 Jun 2002 , Novosibirsk, Russia |
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Journal |
Chemistry for Sustainable Development
ISSN: 1817-1818 |
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Output data | Year: 2003, Volume: 11, Number: 1, Pages: 123-130 Pages count : 8 | ||||||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 00-03-32407 |
Abstract:
Relationship of structure and surface properties of modified titanium dioxides, prepared by alkoxide method using derivatives of phosphoric acid as precursors, with their catalytic performance in the reaction of ethylene glycol ethoxylation was investigated. It was found, that such catalysts are mono-phase, nanocluster ones with anatase structure, and have uniform narrow pore distribution. Catalysts prepared using the amidophosphite precursors provide high catalytic activity due to the high surface acidity, and high selectivity of diethylene glycol formation due to the "sieve effect" and concert acid-base mechanism of ethylene oxide addition.
Paper
Cite:
Kozlovskiy R.A.
, Shvets V.F.
, Kustov A.V.
, Kitaev L.E.
, Yuschenko V.V.
, Kriventsov V.V.
, Kochubey D.I.
, Tsodikov M.V.
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Chemistry for Sustainable Development. 2003. V.11. N1. P.123-130. РИНЦ
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Chemistry for Sustainable Development. 2003. V.11. N1. P.123-130. РИНЦ
Original:
Kozlovskiy R.A.
, Shvets V.F.
, Koustov A.V.
, Kitaev L.E.
, Yushchenko V.V.
, Kriventsov V.V.
, Kochubey D.I.
, Tsodikov M.V.
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Химия в интересах устойчивого развития. 2003. V.11. N1. P.123-130. РИНЦ
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Химия в интересах устойчивого развития. 2003. V.11. N1. P.123-130. РИНЦ
Identifiers:
Elibrary | 30656832 |
Citing:
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