Analysis of the Frequencies and Modes of the Normal Vibrations of Dimethyl Sulfide Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 1979, Volume: 20, Number: 6, Pages: 872-876 Pages count : 5 DOI: 10.1007/BF00753190 | ||
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Abstract:
Models for the force field of dimethyl sulfide and its deuterated analogs are discussed. It is shown that good agreement between the calculated and experimental frequencies can be achieved only by taking account of differences in the electron-density disfribution in the CH bonds lying in and out of the plane of symmetry of the molecule. Two sets of force constants are obtainedfor solving the direct spectral problem with the true and spectroscopic masses of hydrogen and deuterium. These sets can be used as a null approximation for the force field of the DMS ligand in calculations on the corresponding complexes.
Cite:
Burgina E.B.
, Yurchenko E.N.
Analysis of the Frequencies and Modes of the Normal Vibrations of Dimethyl Sulfide
Journal of Structural Chemistry. 1979. V.20. N6. P.872-876. DOI: 10.1007/BF00753190 WOS Scopus РИНЦ
Analysis of the Frequencies and Modes of the Normal Vibrations of Dimethyl Sulfide
Journal of Structural Chemistry. 1979. V.20. N6. P.872-876. DOI: 10.1007/BF00753190 WOS Scopus РИНЦ
Original:
Бургина Е.Б.
, Юрченко Э.Н.
Анализ частот и форм нормальных колебаний диметилсульфида
Журнал структурной химии. 1979. Т.20. №6. С.1013-1018. РИНЦ
Анализ частот и форм нормальных колебаний диметилсульфида
Журнал структурной химии. 1979. Т.20. №6. С.1013-1018. РИНЦ
Dates:
Submitted: | Jul 4, 1978 |
Published print: | Nov 1, 1979 |
Identifiers:
Web of science | WOS:A1979KJ69000008 |
Scopus | 2-s2.0-34250265968 |
Elibrary | 30658211 |
OpenAlex | W2066721073 |
Citing:
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