Analysis of Influence of Kinematics on the Degree of Characteristic Nature of Normal Vibrations of Square-Planar and Tetrahedral Complexes MCl2L2 Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 1988, Volume: 29, Number: 3, Pages: 378-387 Pages count : 10 DOI: 10.1007/BF00743993 | ||
Tags | Physical Chemistry; Inorganic Chemistry; Characteristic Nature; Normal Vibration; Tetrahedral Complex | ||
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Abstract:
A method has been proposed for the quantitative estimation of the degree of characteristic nature of the normal vibrations from the fraction of the total potential energy of a given normal vibration corresponding to the change in the internal coordinates of a selected fragment. The degree of characteristic nature of the normalvibrations of the complexes MCI2L2 relative to the changes in the bond coordinates of the fragment MCI2 for different structures of the coordination site (square planar, tetrahedral, and pseudotetrahedral) and also for different masses of the central atom M and the ligands L has been analyzed. Equations have been proposed, which make it possible to determine the length of a bond M--C1 from the frequency of the characteristic stretching vibration, on the basis of which the value of Rptcl has been used to construct the sequences of the cis- and trans-influence on the state of the Pt-CI bond in a large group of complexes.
Cite:
Burgina E.B.
, Yurchenko E.N.
, Konovalov L.V.
Analysis of Influence of Kinematics on the Degree of Characteristic Nature of Normal Vibrations of Square-Planar and Tetrahedral Complexes MCl2L2
Journal of Structural Chemistry. 1988. V.29. N3. P.378-387. DOI: 10.1007/BF00743993 WOS Scopus РИНЦ
Analysis of Influence of Kinematics on the Degree of Characteristic Nature of Normal Vibrations of Square-Planar and Tetrahedral Complexes MCl2L2
Journal of Structural Chemistry. 1988. V.29. N3. P.378-387. DOI: 10.1007/BF00743993 WOS Scopus РИНЦ
Original:
Бургина Е.Б.
, Юрченко Э.Н.
, Коновалов Л.В.
Анализ влияния кинематики на характеристичность нормальных колебаний плоскоквадратных и тетраэдрических комплексов МСI2L2
Журнал структурной химии. 1988. Т.29. №3. С.38-48. РИНЦ
Анализ влияния кинематики на характеристичность нормальных колебаний плоскоквадратных и тетраэдрических комплексов МСI2L2
Журнал структурной химии. 1988. Т.29. №3. С.38-48. РИНЦ
Dates:
Submitted: | Oct 13, 1986 |
Published print: | May 1, 1988 |
Identifiers:
Web of science | WOS:A1988AL77500006 |
Scopus | 2-s2.0-34250092790 |
Elibrary | 30669600 |
OpenAlex | W2077264344 |