Determination of the Composition and Structure of Paramagnetic Coordination Compounds in Solutions from Data on the Spin Relaxation of Their Nuclei Review
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 1990, Volume: 31, Number: 4, Pages: 622-648 Pages count : 27 DOI: 10.1007/BF00752496 | ||
Tags | Physical Chemistry; Inorganic Chemistry; Coordination Compound; Spin Relaxation | ||
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Abstract:
The theory and practice of the application of nuclear spin relaxation methods to the establishment of the composition and structure of labile paramagnetic complexes of transition metals directly in solutions have been considered.
The factors which complicate the determination of structural characteristics from data on the paramagnetic relaxation rates of the nuclei of metal complexes in solutions have been analyzed. The real possibilities of paramagnetic
relaxation in the measurement of these characteristics have been determined on the basis of this analysis, and a strategy for carrying out such measurements has been formulated. Examples of the study of the structure of complexes
of transition metals by nuclear spin relaxation in real chemical and biological systems have been given.
Cite:
Zamaraev K.I.
, Nekipelov V.M.
Determination of the Composition and Structure of Paramagnetic Coordination Compounds in Solutions from Data on the Spin Relaxation of Their Nuclei
Journal of Structural Chemistry. 1990. V.31. N4. P.622-648. DOI: 10.1007/BF00752496 WOS Scopus РИНЦ
Determination of the Composition and Structure of Paramagnetic Coordination Compounds in Solutions from Data on the Spin Relaxation of Their Nuclei
Journal of Structural Chemistry. 1990. V.31. N4. P.622-648. DOI: 10.1007/BF00752496 WOS Scopus РИНЦ
Original:
Замараев К.И.
, Некипелов В.М.
Определение состава и структуры парамагнитных координационных соединений в растворах из данных о спиновой релаксации и ядер
Журнал структурной химии. 1990. Т.31. №4. С.111-136. РИНЦ
Определение состава и структуры парамагнитных координационных соединений в растворах из данных о спиновой релаксации и ядер
Журнал структурной химии. 1990. Т.31. №4. С.111-136. РИНЦ
Dates:
Submitted: | Jan 3, 1989 |
Published print: | Jul 1, 1990 |
Identifiers:
Web of science | WOS:A1990HQ34800020 |
Scopus | 2-s2.0-34249959334 |
Elibrary | 31432255 |
OpenAlex | W1990569970 |